Abstract
(Matrix presented) Treatment of a mixture of a terminal alkyne and an aldehyde with CrCl2 and a catalytic amount of NiCl2 and triphenylphosphine in the pre of water in DMF at 25°C gives a 1,2-disubstituted allylic alcohol regioselectively.
| Original language | English |
|---|---|
| Pages (from-to) | 653-655 |
| Number of pages | 3 |
| Journal | Organic Letters |
| Volume | 5 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Mar 6 2003 |
Fingerprint
ASJC Scopus subject areas
- Molecular Medicine
Cite this
Regioselective reductive coupling of alkynes and aldehydes leading to allylic alcohols. / Takai, Kazuhiko; Sakamoto, Shuji; Isshiki, Takahiko.
In: Organic Letters, Vol. 5, No. 5, 06.03.2003, p. 653-655.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Regioselective reductive coupling of alkynes and aldehydes leading to allylic alcohols
AU - Takai, Kazuhiko
AU - Sakamoto, Shuji
AU - Isshiki, Takahiko
PY - 2003/3/6
Y1 - 2003/3/6
N2 - (Matrix presented) Treatment of a mixture of a terminal alkyne and an aldehyde with CrCl2 and a catalytic amount of NiCl2 and triphenylphosphine in the pre of water in DMF at 25°C gives a 1,2-disubstituted allylic alcohol regioselectively.
AB - (Matrix presented) Treatment of a mixture of a terminal alkyne and an aldehyde with CrCl2 and a catalytic amount of NiCl2 and triphenylphosphine in the pre of water in DMF at 25°C gives a 1,2-disubstituted allylic alcohol regioselectively.
UR - http://www.scopus.com/inward/record.url?scp=0037538818&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037538818&partnerID=8YFLogxK
U2 - 10.1021/ol0272996
DO - 10.1021/ol0272996
M3 - Article
C2 - 12605482
AN - SCOPUS:0037538818
VL - 5
SP - 653
EP - 655
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 5
ER -