Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

Yasushi Nishihara, Daisuke Saito, Kenki Tanemura, Shintaro Noyori, Kentaro Takagi

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

Original languageEnglish
Pages (from-to)3546-3549
Number of pages4
JournalOrganic Letters
Volume11
Issue number16
DOIs
Publication statusPublished - Aug 20 2009

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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