Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

Yasushi Nishihara, Daisuke Saito, Kenki Tanemura, Shintaro Noyori, Kentaro Takagi

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

Original languageEnglish
Pages (from-to)3546-3549
Number of pages4
JournalOrganic Letters
Volume11
Issue number16
DOIs
Publication statusPublished - Aug 20 2009

Fingerprint

synthesis
vinylsilane

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

Cite this

Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles. / Nishihara, Yasushi; Saito, Daisuke; Tanemura, Kenki; Noyori, Shintaro; Takagi, Kentaro.

In: Organic Letters, Vol. 11, No. 16, 20.08.2009, p. 3546-3549.

Research output: Contribution to journalArticle

Nishihara, Yasushi ; Saito, Daisuke ; Tanemura, Kenki ; Noyori, Shintaro ; Takagi, Kentaro. / Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles. In: Organic Letters. 2009 ; Vol. 11, No. 16. pp. 3546-3549.
@article{259af06365014deab4b3f5ec2971dc87,
title = "Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles",
abstract = "Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.",
author = "Yasushi Nishihara and Daisuke Saito and Kenki Tanemura and Shintaro Noyori and Kentaro Takagi",
year = "2009",
month = "8",
day = "20",
doi = "10.1021/ol901236s",
language = "English",
volume = "11",
pages = "3546--3549",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "16",

}

TY - JOUR

T1 - Regio- and stereoselective synthesis of multisubstituted vinylsilanes via zirconacycles

AU - Nishihara, Yasushi

AU - Saito, Daisuke

AU - Tanemura, Kenki

AU - Noyori, Shintaro

AU - Takagi, Kentaro

PY - 2009/8/20

Y1 - 2009/8/20

N2 - Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

AB - Image Persented A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various alkynylsilanes through zirconacycles such as zirconacyclopropenes and zirconacyclopentenes and the subsequent transformation of the formed alkenylzirconocene complexes.

UR - http://www.scopus.com/inward/record.url?scp=68949142762&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=68949142762&partnerID=8YFLogxK

U2 - 10.1021/ol901236s

DO - 10.1021/ol901236s

M3 - Article

C2 - 19719197

AN - SCOPUS:68949142762

VL - 11

SP - 3546

EP - 3549

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 16

ER -