Abstract
Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.
| Original language | English |
|---|---|
| Pages (from-to) | 1065-1068 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 29 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1988 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Takai, K., Kataoka, Y., Okazoe, T., & Utimoto, K. (1988). Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters. Tetrahedron Letters, 29(9), 1065-1068. https://doi.org/10.1016/0040-4039(88)85336-X