Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters

Kazuhiko Takai; Yasutaka Kataoka; Takashi Okazoe; Kiitiro Utimoto

doi:10.1016/0040-4039(88)85336-X

Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters

Kazuhiko Takai, Yasutaka Kataoka, Takashi Okazoe, Kiitiro Utimoto

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl₄, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.

Original language	English
Pages (from-to)	1065-1068
Number of pages	4
Journal	Tetrahedron Letters
Volume	29
Issue number	9
DOIs	https://doi.org/10.1016/0040-4039(88)85336-X
Publication status	Published - 1988
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/0040-4039(88)85336-X

Cite this

@article{b66a191f711c4f4bab02800a34d56fd5,

title = "Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters",

abstract = "Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.",

author = "Kazuhiko Takai and Yasutaka Kataoka and Takashi Okazoe and Kiitiro Utimoto",

year = "1988",

doi = "10.1016/0040-4039(88)85336-X",

language = "English",

volume = "29",

pages = "1065--1068",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "9",

}

TY - JOUR

T1 - Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters

AU - Takai, Kazuhiko

AU - Kataoka, Yasutaka

AU - Okazoe, Takashi

AU - Utimoto, Kiitiro

PY - 1988

Y1 - 1988

N2 - Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.

AB - Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.

UR - http://www.scopus.com/inward/record.url?scp=0000009407&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000009407&partnerID=8YFLogxK

U2 - 10.1016/0040-4039(88)85336-X

DO - 10.1016/0040-4039(88)85336-X

M3 - Article

AN - SCOPUS:0000009407

VL - 29

SP - 1065

EP - 1068

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 9

ER -

Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this