Abstract
Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.
| Original language | English |
|---|---|
| Pages (from-to) | 1065-1068 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 29 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1988 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
Cite this
Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters. / Takai, Kazuhiko; Kataoka, Yasutaka; Okazoe, Takashi; Utimoto, Kiitiro.
In: Tetrahedron Letters, Vol. 29, No. 9, 1988, p. 1065-1068.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Regio- and stereoselective preparation of silyl enol ethers by alkylidenation of silyl esters
AU - Takai, Kazuhiko
AU - Kataoka, Yasutaka
AU - Okazoe, Takashi
AU - Utimoto, Kiitiro
PY - 1988
Y1 - 1988
N2 - Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.
AB - Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.
UR - http://www.scopus.com/inward/record.url?scp=0000009407&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000009407&partnerID=8YFLogxK
U2 - 10.1016/0040-4039(88)85336-X
DO - 10.1016/0040-4039(88)85336-X
M3 - Article
AN - SCOPUS:0000009407
VL - 29
SP - 1065
EP - 1068
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 9
ER -