Regio- and stereocontrolled hydrosilylation polyaddition catalyzed by RhI(PPh3)3. Syntheses of polymers containing (E)- or (Z)-alkenylsilane moieties

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticle

67 Citations (Scopus)

Abstract

Stereodivergent syntheses of E- and Z-polymers of the alkenylsilane moiety were carried out hand in hand by hydrosilation polyaddition using diethylbenzene and bis(dimethylsily)benzene. Spectroscopic change based on the stereochemistries of polymers was observed.

Original languageEnglish
Pages (from-to)1115-1116
Number of pages2
JournalMacromolecules
Volume33
Issue number4
DOIs
Publication statusPublished - Jan 1 2000
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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