Recyclable palladium catalyst in PEG/CH3CN biphasic system for electro-oxidative wacker-type reaction

Koichi Mitsudo; Satoshi Fukunaga; Tomoya Fujita; Hiroki Mandai; Seiji Suga; Hideo Tanaka

doi:10.5796/electrochemistry.81.347

Recyclable palladium catalyst in PEG/CH₃CN biphasic system for electro-oxidative wacker-type reaction

Koichi Mitsudo, Satoshi Fukunaga, Tomoya Fujita, Hiroki Mandai, Seiji Suga, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Electro-oxidative Wacker-type reaction has been developed in PEG/CH ₃CN thermomorphic biphasic system. The heterogeneous solution was turned into homogeneous solution with heating to 60°C, and electro-oxidative Wackertype reactions of alkenes bearing long alkyl chains proceeded smoothly to afford methyl ketones in good yields. The recycling of PEG phase containing Pd has also been achieved.

Original language	English
Pages (from-to)	347-349
Number of pages	3
Journal	Electrochemistry
Volume	81
Issue number	5
DOIs	https://doi.org/10.5796/electrochemistry.81.347
Publication status	Published - May 2013

Keywords

Biphasic system
Electro-oxidation
PEG
Wacker oxidation

ASJC Scopus subject areas

Electrochemistry

Access to Document

10.5796/electrochemistry.81.347

Cite this

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abstract = "Electro-oxidative Wacker-type reaction has been developed in PEG/CH 3CN thermomorphic biphasic system. The heterogeneous solution was turned into homogeneous solution with heating to 60°C, and electro-oxidative Wackertype reactions of alkenes bearing long alkyl chains proceeded smoothly to afford methyl ketones in good yields. The recycling of PEG phase containing Pd has also been achieved.",

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AU - Mitsudo, Koichi

AU - Fukunaga, Satoshi

AU - Fujita, Tomoya

AU - Mandai, Hiroki

AU - Suga, Seiji

AU - Tanaka, Hideo

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AB - Electro-oxidative Wacker-type reaction has been developed in PEG/CH 3CN thermomorphic biphasic system. The heterogeneous solution was turned into homogeneous solution with heating to 60°C, and electro-oxidative Wackertype reactions of alkenes bearing long alkyl chains proceeded smoothly to afford methyl ketones in good yields. The recycling of PEG phase containing Pd has also been achieved.

KW - Biphasic system

KW - Electro-oxidation

KW - PEG

KW - Wacker oxidation

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