Recyclable palladium catalyst in PEG/CH3CN biphasic system for electro-oxidative wacker-type reaction

Koichi Mitsudo, Satoshi Fukunaga, Tomoya Fujita, Hiroki Mandai, Seiji Suga, Hideo Tanaka

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Electro-oxidative Wacker-type reaction has been developed in PEG/CH 3CN thermomorphic biphasic system. The heterogeneous solution was turned into homogeneous solution with heating to 60°C, and electro-oxidative Wackertype reactions of alkenes bearing long alkyl chains proceeded smoothly to afford methyl ketones in good yields. The recycling of PEG phase containing Pd has also been achieved.

Original languageEnglish
Pages (from-to)347-349
Number of pages3
JournalElectrochemistry
Volume81
Issue number5
DOIs
Publication statusPublished - May 1 2013

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Keywords

  • Biphasic system
  • Electro-oxidation
  • PEG
  • Wacker oxidation

ASJC Scopus subject areas

  • Electrochemistry

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