Recyclable electron transfer system: Electroreduction of viologen in ionic liquids and Pd-catalyzed reductive coupling of aryl halides

Manabu Kuroboshi; Akiko Kuwano; Hideo Tanaka

doi:10.5796/electrochemistry.76.862

Recyclable electron transfer system: Electroreduction of viologen in ionic liquids and Pd-catalyzed reductive coupling of aryl halides

Manabu Kuroboshi, Akiko Kuwano, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Electroreduction of N.N'-dioctyl-4,4′-bipyridinium (C ₈V^2-) bis(triflimide) was carried out in ionic liquids to give the corresponding quinoid C₈V¹, which promoted reductive coupling of aryl halides in the presence of a Pd catalyst to give biaryls. C₈V²⁺ and the ionic liquids were used repeatedly.

Original language	English
Pages (from-to)	862-864
Number of pages	3
Journal	Electrochemistry
Volume	76
Issue number	12
DOIs	https://doi.org/10.5796/electrochemistry.76.862
Publication status	Published - Dec 2008

Keywords

Aryl halide
Ionic liquid
Palladium
Reductive coupling
Viologen

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.76.862

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abstract = "Electroreduction of N.N'-dioctyl-4,4′-bipyridinium (C 8V2-) bis(triflimide) was carried out in ionic liquids to give the corresponding quinoid C8V1, which promoted reductive coupling of aryl halides in the presence of a Pd catalyst to give biaryls. C8V2+ and the ionic liquids were used repeatedly.",

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author = "Manabu Kuroboshi and Akiko Kuwano and Hideo Tanaka",

year = "2008",

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language = "English",

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AU - Kuwano, Akiko

AU - Tanaka, Hideo

PY - 2008/12

Y1 - 2008/12

N2 - Electroreduction of N.N'-dioctyl-4,4′-bipyridinium (C 8V2-) bis(triflimide) was carried out in ionic liquids to give the corresponding quinoid C8V1, which promoted reductive coupling of aryl halides in the presence of a Pd catalyst to give biaryls. C8V2+ and the ionic liquids were used repeatedly.

AB - Electroreduction of N.N'-dioctyl-4,4′-bipyridinium (C 8V2-) bis(triflimide) was carried out in ionic liquids to give the corresponding quinoid C8V1, which promoted reductive coupling of aryl halides in the presence of a Pd catalyst to give biaryls. C8V2+ and the ionic liquids were used repeatedly.

KW - Aryl halide

KW - Ionic liquid

KW - Palladium

KW - Reductive coupling

KW - Viologen

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JF - Electrochemistry

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ER -

Recyclable electron transfer system: Electroreduction of viologen in ionic liquids and Pd-catalyzed reductive coupling of aryl halides

Abstract

Keywords

ASJC Scopus subject areas

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