Recognition of chirality and residual groups of amino acid esters using new trifunctional chiral porphyrins with C2 symmetry

Tadashi Mizutani, Tadashi Ema, Takashi Tomita, Yasuhisa Kuroda, Hisanobu Ogoshi

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

An intrinsic chiral recognition host, [trans-5,15-bis(2-hydroxyphenyl)-10- {2,6-bis(methoxycarbonylmethyl)phenyl}-2,3,17,18-tetraethylporphyrinato]zinc(II) 1, is synthesized and found to show an enantioselectivity of ca. 2: 1 for L- and D-amino acid esters having non-polar residues, whereas it shows a reversed enantioselectivity of ca. 1: 2 for L- and D-Ser-OBzl.

Original languageEnglish
Pages (from-to)520-522
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number6
DOIs
Publication statusPublished - Dec 1 1993
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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