Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts

Hiroki Mandai, Kazuki Fujii, Seiji Suga

Research output: Contribution to journalReview article

9 Citations (Scopus)

Abstract

This digest focuses on recent topics in intra- and intermolecular enantioselective acyl transfer reactions with dialkylaminopyridine-based catalysts over the past decade (2007–2017). The structures of the catalysts are divided into four categories according to the location of the chiral environment (C2, C3, or C4 position of pyridine, and miscellaneous). The role of the structure in the enantioselective acyl transfer reaction and the reaction mechanism will be discussed briefly.

Original languageEnglish
Pages (from-to)1787-1803
Number of pages17
JournalTetrahedron Letters
Volume59
Issue number19
DOIs
Publication statusPublished - May 9 2018

Keywords

  • Acyl transfer reaction
  • Dialkylaminopyridine-based catalysts
  • Enantioselective reaction
  • Nucleohilic catalyst
  • Organocatalyst

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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