Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts

Hiroki Mandai; Kazuki Fujii; Seiji Suga

doi:10.1016/j.tetlet.2018.03.016

Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts

Hiroki Mandai, Kazuki Fujii, Seiji Suga

Research output: Contribution to journal › Review article › peer-review

28 Citations (Scopus)

Abstract

This digest focuses on recent topics in intra- and intermolecular enantioselective acyl transfer reactions with dialkylaminopyridine-based catalysts over the past decade (2007–2017). The structures of the catalysts are divided into four categories according to the location of the chiral environment (C2, C3, or C4 position of pyridine, and miscellaneous). The role of the structure in the enantioselective acyl transfer reaction and the reaction mechanism will be discussed briefly.

Original language	English
Pages (from-to)	1787-1803
Number of pages	17
Journal	Tetrahedron Letters
Volume	59
Issue number	19
DOIs	https://doi.org/10.1016/j.tetlet.2018.03.016
Publication status	Published - May 9 2018

Keywords

Acyl transfer reaction
Dialkylaminopyridine-based catalysts
Enantioselective reaction
Nucleohilic catalyst
Organocatalyst

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2018.03.016

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title = "Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts",

abstract = "This digest focuses on recent topics in intra- and intermolecular enantioselective acyl transfer reactions with dialkylaminopyridine-based catalysts over the past decade (2007–2017). The structures of the catalysts are divided into four categories according to the location of the chiral environment (C2, C3, or C4 position of pyridine, and miscellaneous). The role of the structure in the enantioselective acyl transfer reaction and the reaction mechanism will be discussed briefly.",

keywords = "Acyl transfer reaction, Dialkylaminopyridine-based catalysts, Enantioselective reaction, Nucleohilic catalyst, Organocatalyst",

author = "Hiroki Mandai and Kazuki Fujii and Seiji Suga",

note = "Funding Information: This research was partially supported by a Grant-in-Aid for Young Scientists (B) (No 17K17903) from JSPS , a Grant-in-Aid for Scientific Research on Innovative Areas “Advanced Molecular Transformations by Organocatalysts”, and JGC-S SCHOLARSHIP FOUNDATION. Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",

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doi = "10.1016/j.tetlet.2018.03.016",

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T1 - Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts

AU - Mandai, Hiroki

AU - Fujii, Kazuki

AU - Suga, Seiji

N1 - Funding Information: This research was partially supported by a Grant-in-Aid for Young Scientists (B) (No 17K17903) from JSPS , a Grant-in-Aid for Scientific Research on Innovative Areas “Advanced Molecular Transformations by Organocatalysts”, and JGC-S SCHOLARSHIP FOUNDATION. Publisher Copyright: © 2018 Elsevier Ltd

PY - 2018/5/9

Y1 - 2018/5/9

N2 - This digest focuses on recent topics in intra- and intermolecular enantioselective acyl transfer reactions with dialkylaminopyridine-based catalysts over the past decade (2007–2017). The structures of the catalysts are divided into four categories according to the location of the chiral environment (C2, C3, or C4 position of pyridine, and miscellaneous). The role of the structure in the enantioselective acyl transfer reaction and the reaction mechanism will be discussed briefly.

AB - This digest focuses on recent topics in intra- and intermolecular enantioselective acyl transfer reactions with dialkylaminopyridine-based catalysts over the past decade (2007–2017). The structures of the catalysts are divided into four categories according to the location of the chiral environment (C2, C3, or C4 position of pyridine, and miscellaneous). The role of the structure in the enantioselective acyl transfer reaction and the reaction mechanism will be discussed briefly.

KW - Acyl transfer reaction

KW - Dialkylaminopyridine-based catalysts

KW - Enantioselective reaction

KW - Nucleohilic catalyst

KW - Organocatalyst

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SN - 0040-4039

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Recent topics in enantioselective acyl transfer reactions with dialkylaminopyridine-based nucleophilic catalysts

Abstract

Keywords

ASJC Scopus subject areas

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