Recent structural investigations of metallic polymers

J. P. Pouget, Z. Oblakowski, Yoshio Nogami, P. A. Albouy, M. Laridjani, E. J. Oh, Y. Min, A. G. MacDiarmid, J. Tsukamoto, T. Ishiguro, A. J. Epstein

Research output: Contribution to journalArticle

125 Citations (Scopus)

Abstract

Recent structural studies of the undoped and iodine-doped polyacetylenes (prepared by the Tsukamoto and co-workers method), PF6--doped polypyrrole and polyaniline emeraldine base and (hydrochloric acid and camphorsulfonic acid) salts are presented. Some key features of the polymer chain array and its evolution with the conditions of preparation are emphasized. Special attention has been devoted to characterization of the various sources of structural disorder in the relationship with high conductivity and related properties exhibited by these three families of polymers. Variation in the structural order in both crystalline and amorphous regions correlates directly with the electrical and optical properties of the metallic state.

Original languageEnglish
Pages (from-to)131-140
Number of pages10
JournalSynthetic Metals
Volume65
Issue number2-3
DOIs
Publication statusPublished - 1994
Externally publishedYes

Fingerprint

Polymers
Polyacetylenes
Hydrochloric Acid
polyacetylene
hydrochloric acid
polypyrroles
Polypyrroles
polymers
Hydrochloric acid
Polyaniline
Iodine
iodine
Electric properties
Optical properties
Salts
electrical properties
disorders
Crystalline materials
salts
optical properties

Keywords

  • Metallic polymers
  • Structure

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Pouget, J. P., Oblakowski, Z., Nogami, Y., Albouy, P. A., Laridjani, M., Oh, E. J., ... Epstein, A. J. (1994). Recent structural investigations of metallic polymers. Synthetic Metals, 65(2-3), 131-140. https://doi.org/10.1016/0379-6779(94)90174-0

Recent structural investigations of metallic polymers. / Pouget, J. P.; Oblakowski, Z.; Nogami, Yoshio; Albouy, P. A.; Laridjani, M.; Oh, E. J.; Min, Y.; MacDiarmid, A. G.; Tsukamoto, J.; Ishiguro, T.; Epstein, A. J.

In: Synthetic Metals, Vol. 65, No. 2-3, 1994, p. 131-140.

Research output: Contribution to journalArticle

Pouget, JP, Oblakowski, Z, Nogami, Y, Albouy, PA, Laridjani, M, Oh, EJ, Min, Y, MacDiarmid, AG, Tsukamoto, J, Ishiguro, T & Epstein, AJ 1994, 'Recent structural investigations of metallic polymers', Synthetic Metals, vol. 65, no. 2-3, pp. 131-140. https://doi.org/10.1016/0379-6779(94)90174-0
Pouget JP, Oblakowski Z, Nogami Y, Albouy PA, Laridjani M, Oh EJ et al. Recent structural investigations of metallic polymers. Synthetic Metals. 1994;65(2-3):131-140. https://doi.org/10.1016/0379-6779(94)90174-0
Pouget, J. P. ; Oblakowski, Z. ; Nogami, Yoshio ; Albouy, P. A. ; Laridjani, M. ; Oh, E. J. ; Min, Y. ; MacDiarmid, A. G. ; Tsukamoto, J. ; Ishiguro, T. ; Epstein, A. J. / Recent structural investigations of metallic polymers. In: Synthetic Metals. 1994 ; Vol. 65, No. 2-3. pp. 131-140.
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