Rearrangement of indene skeletons under mild conditions

Yoichiro Kuninobu, Hirokazu Ueda, Atsushi Kawata, Kazuhiko Takai

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

(Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditions or the irradiation of light, this rearrangement proceeds at room temperature without UV light irradiation. An amino group at the 3-position plays an important role to accelerate the rearrangement under mild conditions.

Original languageEnglish
Pages (from-to)6749-6752
Number of pages4
JournalJournal of Organic Chemistry
Volume72
Issue number18
DOIs
Publication statusPublished - Aug 31 2007

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Irradiation
Isomerization
Ultraviolet radiation
Isomers
Derivatives
Temperature
indene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Rearrangement of indene skeletons under mild conditions. / Kuninobu, Yoichiro; Ueda, Hirokazu; Kawata, Atsushi; Takai, Kazuhiko.

In: Journal of Organic Chemistry, Vol. 72, No. 18, 31.08.2007, p. 6749-6752.

Research output: Contribution to journalArticle

Kuninobu, Yoichiro ; Ueda, Hirokazu ; Kawata, Atsushi ; Takai, Kazuhiko. / Rearrangement of indene skeletons under mild conditions. In: Journal of Organic Chemistry. 2007 ; Vol. 72, No. 18. pp. 6749-6752.
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