Rearrangement of indene skeletons under mild conditions

Yoichiro Kuninobu, Hirokazu Ueda, Atsushi Kawata, Kazuhiko Takai

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

(Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditions or the irradiation of light, this rearrangement proceeds at room temperature without UV light irradiation. An amino group at the 3-position plays an important role to accelerate the rearrangement under mild conditions.

Original languageEnglish
Pages (from-to)6749-6752
Number of pages4
JournalJournal of Organic Chemistry
Volume72
Issue number18
DOIs
Publication statusPublished - Aug 31 2007

ASJC Scopus subject areas

  • Organic Chemistry

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