Rearrangement of indene skeletons under mild conditions

Yoichiro Kuninobu; Hirokazu Ueda; Atsushi Kawata; Kazuhiko Takai

doi:10.1021/jo070537w

Rearrangement of indene skeletons under mild conditions

Yoichiro Kuninobu, Hirokazu Ueda, Atsushi Kawata, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

(Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditions or the irradiation of light, this rearrangement proceeds at room temperature without UV light irradiation. An amino group at the 3-position plays an important role to accelerate the rearrangement under mild conditions.

Original language	English
Pages (from-to)	6749-6752
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	72
Issue number	18
DOIs	https://doi.org/10.1021/jo070537w
Publication status	Published - Aug 31 2007
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo070537w

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abstract = "(Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditions or the irradiation of light, this rearrangement proceeds at room temperature without UV light irradiation. An amino group at the 3-position plays an important role to accelerate the rearrangement under mild conditions.",

author = "Yoichiro Kuninobu and Hirokazu Ueda and Atsushi Kawata and Kazuhiko Takai",

year = "2007",

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AU - Kuninobu, Yoichiro

AU - Ueda, Hirokazu

AU - Kawata, Atsushi

AU - Takai, Kazuhiko

PY - 2007/8/31

Y1 - 2007/8/31

N2 - (Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditions or the irradiation of light, this rearrangement proceeds at room temperature without UV light irradiation. An amino group at the 3-position plays an important role to accelerate the rearrangement under mild conditions.

AB - (Chemical Equation Presented) Isomerization between two isomers of 1,2-disubstituted 3-aminoindenes occurs via the rearrangement of indene frameworks. In contrast to previous rearrangements of indene derivatives, which occur under high-temperature conditions or the irradiation of light, this rearrangement proceeds at room temperature without UV light irradiation. An amino group at the 3-position plays an important role to accelerate the rearrangement under mild conditions.

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Rearrangement of indene skeletons under mild conditions

Abstract

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