Reactivity of surface hydroxyl groups with metal complex compounds

T. Yamada, Y. Kuroda, A. Fukuoka, M. Ichikawa, K. Tanaka

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The surface reaction of the adsorbed hydroxyl group OH(a) with Rh(CO)2(π-C3H5) delivered from the gas phase: OH (a) + Rh(CO)2(π-C3H5)(g) → O-Rh( CO )2(a) + C3H6(a/g) has been studied on Ni(110), Ni(100) and ZnO(1010) mainly by HREELS and TPRS. On Ni(110), p(2×1)-OH(a) was completely diminished by adsorption of Rh(CO)2(π-C3H5) below 300 K. C3H6 stayed on the surface after this reaction. On Zn(1010) OH(a) was deposited with surface defects indroduced by Ar ion bombardment. The same reaction occurred with OH(a) on ZnO(1010), but not completely on Ni(100) which was covered with oxide layers.

Original languageEnglish
Pages (from-to)845-854
Number of pages10
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume54-55
Issue numberC
DOIs
Publication statusPublished - 1990

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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