Reactivity of surface hydroxyl groups with metal complex compounds

T. Yamada, Yasushige Kuroda, A. Fukuoka, M. Ichikawa, K. Tanaka

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The surface reaction of the adsorbed hydroxyl group OH(a) with Rh(CO)2(π-C3H5) delivered from the gas phase: OH (a) + Rh(CO)2(π-C3H5)(g) → O-Rh( CO )2(a) + C3H6(a/g) has been studied on Ni(110), Ni(100) and ZnO(1010) mainly by HREELS and TPRS. On Ni(110), p(2×1)-OH(a) was completely diminished by adsorption of Rh(CO)2(π-C3H5) below 300 K. C3H6 stayed on the surface after this reaction. On Zn(1010) OH(a) was deposited with surface defects indroduced by Ar ion bombardment. The same reaction occurred with OH(a) on ZnO(1010), but not completely on Ni(100) which was covered with oxide layers.

Original languageEnglish
Pages (from-to)845-854
Number of pages10
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume54-55
Issue numberC
DOIs
Publication statusPublished - 1990

Fingerprint

complex compounds
Coordination Complexes
Surface defects
Surface reactions
Carbon Monoxide
Ion bombardment
Metal complexes
Hydroxyl Radical
reactivity
Adsorption
Oxides
surface defects
Gases
metals
surface reactions
bombardment
vapor phases
adsorption
oxides
ions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Reactivity of surface hydroxyl groups with metal complex compounds. / Yamada, T.; Kuroda, Yasushige; Fukuoka, A.; Ichikawa, M.; Tanaka, K.

In: Journal of Electron Spectroscopy and Related Phenomena, Vol. 54-55, No. C, 1990, p. 845-854.

Research output: Contribution to journalArticle

Yamada, T. ; Kuroda, Yasushige ; Fukuoka, A. ; Ichikawa, M. ; Tanaka, K. / Reactivity of surface hydroxyl groups with metal complex compounds. In: Journal of Electron Spectroscopy and Related Phenomena. 1990 ; Vol. 54-55, No. C. pp. 845-854.
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