Reactions of iodinated vinylidene complexes generated from 1-Iodo-1-alkynes and W(CO)5(thf)

Tomoya Miura, Nobuharu Iwasawa

Research output: Contribution to journalArticlepeer-review

161 Citations (Scopus)

Abstract

We have succeeded in generating iodinated tungsten vinylidene complexes from 1-iodo-1-alkynes and W(CO)5(thf), and have employed these complexes for two types of synthetically useful reactions, that is, 6π-electrocyclization for o-(iodoethynyl)styrenes and endo-selective cyclization for ω-iodoacetylenic silyl enol ethers.

Original languageEnglish
Pages (from-to)518-519
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number4
DOIs
Publication statusPublished - Jan 30 2002
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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