Abstract
The reaction of a N-acyliminium ion pool with benzylsilane proceeds by a chain mechanism involving oxidative C-Si bond cleavage. A radical/cation/radical cation crossover mechanism involving single electron transfer has been proposed. The effective binary system consisting of a stoichiometric amount of a benzylsilane and a catalytic amount of a more easily oxidized benzylstannane has been developed.
| Original language | English |
|---|---|
| Pages (from-to) | 1902-1903 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 129 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Feb 21 2007 |
| Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Cite this
Maruyama, T., Mizuno, Y., Shimizu, I., Suga, S., & Yoshida, J. I. (2007). Reactions of a N-acyliminium ion pool with benzylsilanes. Implication of a radical/cation/radical cation chain mechanism involving oxidative C-Si bond cleavage. Journal of the American Chemical Society, 129(7), 1902-1903. https://doi.org/10.1021/ja068589a