Reaction of (α-thioalkyl)chromium compounds prepared by chromium(II) reduction of α-halo sulfides

Shigeki Nakatsukasa, Kazuhiko Takai, Kiitiro Utimoto

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Reduction of α-chloroalkyl phenyl (or methyl) sulfides with chromium(II) chloride in THF proceeds smoothly in the presence of LiI. The resulting (α-thioalkyl)chromium reagents add to aldehydes in a chemo- and stereoselective manner.

Original languageEnglish
Pages (from-to)5045-5046
Number of pages2
JournalJournal of Organic Chemistry
Volume51
Issue number25
Publication statusPublished - 1986
Externally publishedYes

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Chromium Compounds
Sulfides
Chromium
Aldehydes
Chlorides

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Reaction of (α-thioalkyl)chromium compounds prepared by chromium(II) reduction of α-halo sulfides. / Nakatsukasa, Shigeki; Takai, Kazuhiko; Utimoto, Kiitiro.

In: Journal of Organic Chemistry, Vol. 51, No. 25, 1986, p. 5045-5046.

Research output: Contribution to journalArticle

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