Raman study of Cs3C60 under ambient pressure

Y. Kubozono; S. Fujiki; K. Hiraoka; T. Urakawa; Y. Takabayashi; S. Kashino; Y. Iwasa; H. Kitagawa; Y. Mitani

doi:10.1016/S0009-2614(98)01220-2

Raman study of Cs₃C₆₀ under ambient pressure

Y. Kubozono, S. Fujiki, K. Hiraoka, T. Urakawa, Y. Takabayashi, S. Kashino, Y. Iwasa, H. Kitagawa, Y. Mitani

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Temperature dependence of Raman scattering in a pressure-induced superconductor Cs₃C₆₀ was studied under ambient pressure between 2 and 290 K. The contributions of the intramolecular vibration modes to electron-phonon coupling were evaluated by comparing the linewidths of the modes in Cs₃C₆₀ with those in pristine C₆₀. The total electron-phonon coupling constant λ was ≈0.18, approximately one-third of the values for Rb₃C₆₀ and K₃C₆₀. Temperature-dependent Raman scattering in the superconductor Rb₃C₆₀ and a non-superconductor Rb₆C₆₀ was also measured for comparison.

Original language	English
Pages (from-to)	335-340
Number of pages	6
Journal	Chemical Physics Letters
Volume	298
Issue number	4-6
DOIs	https://doi.org/10.1016/S0009-2614(98)01220-2
Publication status	Published - 1998

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/S0009-2614(98)01220-2

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title = "Raman study of Cs3C60 under ambient pressure",

abstract = "Temperature dependence of Raman scattering in a pressure-induced superconductor Cs3C60 was studied under ambient pressure between 2 and 290 K. The contributions of the intramolecular vibration modes to electron-phonon coupling were evaluated by comparing the linewidths of the modes in Cs3C60 with those in pristine C60. The total electron-phonon coupling constant λ was ≈0.18, approximately one-third of the values for Rb3C60 and K3C60. Temperature-dependent Raman scattering in the superconductor Rb3C60 and a non-superconductor Rb6C60 was also measured for comparison.",

author = "Y. Kubozono and S. Fujiki and K. Hiraoka and T. Urakawa and Y. Takabayashi and S. Kashino and Y. Iwasa and H. Kitagawa and Y. Mitani",

year = "1998",

doi = "10.1016/S0009-2614(98)01220-2",

language = "English",

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journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Raman study of Cs3C60 under ambient pressure

AU - Kubozono, Y.

AU - Fujiki, S.

AU - Hiraoka, K.

AU - Urakawa, T.

AU - Takabayashi, Y.

AU - Kashino, S.

AU - Iwasa, Y.

AU - Kitagawa, H.

AU - Mitani, Y.

PY - 1998

Y1 - 1998

N2 - Temperature dependence of Raman scattering in a pressure-induced superconductor Cs3C60 was studied under ambient pressure between 2 and 290 K. The contributions of the intramolecular vibration modes to electron-phonon coupling were evaluated by comparing the linewidths of the modes in Cs3C60 with those in pristine C60. The total electron-phonon coupling constant λ was ≈0.18, approximately one-third of the values for Rb3C60 and K3C60. Temperature-dependent Raman scattering in the superconductor Rb3C60 and a non-superconductor Rb6C60 was also measured for comparison.

AB - Temperature dependence of Raman scattering in a pressure-induced superconductor Cs3C60 was studied under ambient pressure between 2 and 290 K. The contributions of the intramolecular vibration modes to electron-phonon coupling were evaluated by comparing the linewidths of the modes in Cs3C60 with those in pristine C60. The total electron-phonon coupling constant λ was ≈0.18, approximately one-third of the values for Rb3C60 and K3C60. Temperature-dependent Raman scattering in the superconductor Rb3C60 and a non-superconductor Rb6C60 was also measured for comparison.

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DO - 10.1016/S0009-2614(98)01220-2

M3 - Article

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SP - 335

EP - 340

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

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