Raman Spectra and Constitution of Binary Tellurite Glasses Containing Typical Network Modifying Cations

Akiyoshi Osaka; Qiu Jianrong; Tatsuo Fujii; Tokuro Nanba; Jun Takada; Yoshinari Miura

doi:10.2472/jsms.42.473

Raman Spectra and Constitution of Binary Tellurite Glasses Containing Typical Network Modifying Cations

Akiyoshi Osaka, Qiu Jianrong, Tatsuo Fujii, Tokuro Nanba, Jun Takada, Yoshinari Miura

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The 720 and 780 cm^-1 components of the deconvoluted Raman spectra of glasses in the systems R_nO-TeO₂ (R=Li, Na, K, Ba, Zn) were attributed to TeO₃ groups and the 665 cm^-1 band was to TeO₄ groups. The theoretical values of the molar ratio TeO₃/TeO₄ derived from an assumed vitrification reaction were compared with the ratio derived from the intensity ratios of the Raman bands, I(720) /I(665) and I(780)/I(665). It was indicated that [O_2/2Te=O] and [O_1/2Te(=O)-O]^- units were induced by the addition of network modifying oxides in the composition range of lower atomic ratio O/Te. It was proposed that the decrease in the rate of increase of the ratio TeO₃/TeO₄ in the range of larger O/Te was due to the equilibrium TeO_4/2↔[O12/2Te=O] favoring the former unit.

Original language	English
Pages (from-to)	473-477
Number of pages	5
Journal	journal of the society of materials science, japan
Volume	42
Issue number	476
DOIs	https://doi.org/10.2472/jsms.42.473
Publication status	Published - 1993

Keywords

Constitution
Glass
Raman spectrum
Tellurite

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.2472/jsms.42.473

Cite this

@article{ab51acffbb9a48b7b16f8bb2cf9f6609,

title = "Raman Spectra and Constitution of Binary Tellurite Glasses Containing Typical Network Modifying Cations",

abstract = "The 720 and 780 cm-1 components of the deconvoluted Raman spectra of glasses in the systems RnO-TeO2 (R=Li, Na, K, Ba, Zn) were attributed to TeO3 groups and the 665 cm-1 band was to TeO4 groups. The theoretical values of the molar ratio TeO3/TeO4 derived from an assumed vitrification reaction were compared with the ratio derived from the intensity ratios of the Raman bands, I(720) /I(665) and I(780)/I(665). It was indicated that [O2/2Te=O] and [O1/2Te(=O)-O]- units were induced by the addition of network modifying oxides in the composition range of lower atomic ratio O/Te. It was proposed that the decrease in the rate of increase of the ratio TeO3/TeO4 in the range of larger O/Te was due to the equilibrium TeO4/2↔[O12/2Te=O] favoring the former unit.",

keywords = "Constitution, Glass, Raman spectrum, Tellurite",

author = "Akiyoshi Osaka and Qiu Jianrong and Tatsuo Fujii and Tokuro Nanba and Jun Takada and Yoshinari Miura",

year = "1993",

doi = "10.2472/jsms.42.473",

language = "English",

volume = "42",

pages = "473--477",

journal = "Zairyo/Journal of the Society of Materials Science, Japan",

issn = "0514-5163",

publisher = "Society of Materials Science Japan",

number = "476",

}

TY - JOUR

T1 - Raman Spectra and Constitution of Binary Tellurite Glasses Containing Typical Network Modifying Cations

AU - Osaka, Akiyoshi

AU - Jianrong, Qiu

AU - Fujii, Tatsuo

AU - Nanba, Tokuro

AU - Takada, Jun

AU - Miura, Yoshinari

PY - 1993

Y1 - 1993

N2 - The 720 and 780 cm-1 components of the deconvoluted Raman spectra of glasses in the systems RnO-TeO2 (R=Li, Na, K, Ba, Zn) were attributed to TeO3 groups and the 665 cm-1 band was to TeO4 groups. The theoretical values of the molar ratio TeO3/TeO4 derived from an assumed vitrification reaction were compared with the ratio derived from the intensity ratios of the Raman bands, I(720) /I(665) and I(780)/I(665). It was indicated that [O2/2Te=O] and [O1/2Te(=O)-O]- units were induced by the addition of network modifying oxides in the composition range of lower atomic ratio O/Te. It was proposed that the decrease in the rate of increase of the ratio TeO3/TeO4 in the range of larger O/Te was due to the equilibrium TeO4/2↔[O12/2Te=O] favoring the former unit.

AB - The 720 and 780 cm-1 components of the deconvoluted Raman spectra of glasses in the systems RnO-TeO2 (R=Li, Na, K, Ba, Zn) were attributed to TeO3 groups and the 665 cm-1 band was to TeO4 groups. The theoretical values of the molar ratio TeO3/TeO4 derived from an assumed vitrification reaction were compared with the ratio derived from the intensity ratios of the Raman bands, I(720) /I(665) and I(780)/I(665). It was indicated that [O2/2Te=O] and [O1/2Te(=O)-O]- units were induced by the addition of network modifying oxides in the composition range of lower atomic ratio O/Te. It was proposed that the decrease in the rate of increase of the ratio TeO3/TeO4 in the range of larger O/Te was due to the equilibrium TeO4/2↔[O12/2Te=O] favoring the former unit.

KW - Constitution

KW - Glass

KW - Raman spectrum

KW - Tellurite

UR - http://www.scopus.com/inward/record.url?scp=85004267222&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85004267222&partnerID=8YFLogxK

U2 - 10.2472/jsms.42.473

DO - 10.2472/jsms.42.473

M3 - Article

AN - SCOPUS:85004267222

SN - 0514-5163

VL - 42

SP - 473

EP - 477

JO - Zairyo/Journal of the Society of Materials Science, Japan

JF - Zairyo/Journal of the Society of Materials Science, Japan

IS - 476

ER -

Raman Spectra and Constitution of Binary Tellurite Glasses Containing Typical Network Modifying Cations

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this