Radical addition to "cation pool". Reverse process of radical cation fragmentation

Tomokazu Maruyama; Seiji Suga; Jun Ichi Yoshida

doi:10.1021/ja0511218

Radical addition to "cation pool". Reverse process of radical cation fragmentation

Tomokazu Maruyama, Seiji Suga, Jun Ichi Yoshida

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.

Original language	English
Pages (from-to)	7324-7325
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	20
DOIs	https://doi.org/10.1021/ja0511218
Publication status	Published - May 25 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0511218

Cite this

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abstract = "The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.",

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year = "2005",

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doi = "10.1021/ja0511218",

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AU - Maruyama, Tomokazu

AU - Suga, Seiji

AU - Yoshida, Jun Ichi

PY - 2005/5/25

Y1 - 2005/5/25

N2 - The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.

AB - The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.

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DO - 10.1021/ja0511218

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EP - 7325

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

Radical addition to "cation pool". Reverse process of radical cation fragmentation

Abstract

ASJC Scopus subject areas

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