Abstract
Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.
| Original language | English |
|---|---|
| Pages (from-to) | 1023-1026 |
| Number of pages | 4 |
| Journal | Journal of Physics and Chemistry of Solids |
| Volume | 54 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - Sep 1993 |
| Externally published | Yes |
Keywords
- Manganese phosphorus trichalcogenide
- intercalation compound
- pyridinium-pyridine complex
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Fingerprint Dive into the research topics of 'Pyridine-intercalated MnPS<sub>3</sub> single crystals'. Together they form a unique fingerprint.
Cite this
Miyazaki, T., Ichimura, K., Matsuzaki, S., & Sano, M. (1993). Pyridine-intercalated MnPS3 single crystals. Journal of Physics and Chemistry of Solids, 54(9), 1023-1026. https://doi.org/10.1016/0022-3697(93)90008-F