TY - JOUR
T1 - Pyridine-intercalated MnPS3 single crystals
AU - Miyazaki, Takafumi
AU - Ichimura, Kenji
AU - Matsuzaki, Susumu
AU - Sano, Mizuka
N1 - Funding Information:
Acknow~&ements--The authors express their thanks to Japan SpectroscopicC o. for the measummento f polar&d i.r. spectra.T his work was part&By supported by a Grant-in-Aid for SeientigcR eseamhN o. 03450414 from the Ministry of Education,! %iencea nd Culture of Japan.
PY - 1993/9
Y1 - 1993/9
N2 - Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.
AB - Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.
KW - Manganese phosphorus trichalcogenide
KW - intercalation compound
KW - pyridinium-pyridine complex
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U2 - 10.1016/0022-3697(93)90008-F
DO - 10.1016/0022-3697(93)90008-F
M3 - Article
AN - SCOPUS:0006796273
VL - 54
SP - 1023
EP - 1026
JO - Journal of Physics and Chemistry of Solids
JF - Journal of Physics and Chemistry of Solids
SN - 0022-3697
IS - 9
ER -