Pyridine-intercalated MnPS3 single crystals

Takafumi Miyazaki, Kenji Ichimura, Susumu Matsuzaki, Mizuka Sano

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.

Original languageEnglish
Pages (from-to)1023-1026
Number of pages4
JournalJournal of Physics and Chemistry of Solids
Volume54
Issue number9
DOIs
Publication statusPublished - 1993
Externally publishedYes

Fingerprint

Pyridine
pyridines
Single crystals
single crystals
Crystals
Molecules
Vibrational spectra
X ray powder diffraction
vibrational spectra
crystals
Cations
molecules
Hydrogen
interlayers
arcs
Positive ions
pyridine
cations
symmetry
hydrogen

Keywords

  • intercalation compound
  • Manganese phosphorus trichalcogenide
  • pyridinium-pyridine complex

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

Pyridine-intercalated MnPS3 single crystals. / Miyazaki, Takafumi; Ichimura, Kenji; Matsuzaki, Susumu; Sano, Mizuka.

In: Journal of Physics and Chemistry of Solids, Vol. 54, No. 9, 1993, p. 1023-1026.

Research output: Contribution to journalArticle

Miyazaki, Takafumi ; Ichimura, Kenji ; Matsuzaki, Susumu ; Sano, Mizuka. / Pyridine-intercalated MnPS3 single crystals. In: Journal of Physics and Chemistry of Solids. 1993 ; Vol. 54, No. 9. pp. 1023-1026.
@article{314a284a23b9443a96ea0b3c5df492bb,
title = "Pyridine-intercalated MnPS3 single crystals",
abstract = "Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.",
keywords = "intercalation compound, Manganese phosphorus trichalcogenide, pyridinium-pyridine complex",
author = "Takafumi Miyazaki and Kenji Ichimura and Susumu Matsuzaki and Mizuka Sano",
year = "1993",
doi = "10.1016/0022-3697(93)90008-F",
language = "English",
volume = "54",
pages = "1023--1026",
journal = "Journal of Physics and Chemistry of Solids",
issn = "0022-3697",
publisher = "Elsevier Limited",
number = "9",

}

TY - JOUR

T1 - Pyridine-intercalated MnPS3 single crystals

AU - Miyazaki, Takafumi

AU - Ichimura, Kenji

AU - Matsuzaki, Susumu

AU - Sano, Mizuka

PY - 1993

Y1 - 1993

N2 - Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.

AB - Vibrational spectra of pyridine-intercalated MnPS3 (Py-MnPS3) crystals reveal that a part of pyridine molecules in the interlayer space of MnPS3 are converted to pyridinium cations (PyH+) and then form hydrogen-bonded complexes with neutral pyridine molecules. Powder X-ray diffraction and polarized i.r. reflection spectra of Py-MnPS3 crystals indicate that the majority of molecular planes of PyH+ as well as neutral pyridine arc oriented perpendicularly to the layers of MnPS3 with the C2 symmetry axes parallel to the layers.

KW - intercalation compound

KW - Manganese phosphorus trichalcogenide

KW - pyridinium-pyridine complex

UR - http://www.scopus.com/inward/record.url?scp=0006796273&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0006796273&partnerID=8YFLogxK

U2 - 10.1016/0022-3697(93)90008-F

DO - 10.1016/0022-3697(93)90008-F

M3 - Article

AN - SCOPUS:0006796273

VL - 54

SP - 1023

EP - 1026

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

SN - 0022-3697

IS - 9

ER -