Pulsed neutron diffraction study of NaNO2 and KNO2 pure melts

Yasuhiko Iwadate, Takumi Harada, Takahiro Ohkubo, Kazuko Fukushima, Masakatsu Misawa, Toshiharu Fukunaga, Keiji Itoh

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The short-range structural parameters for NaNO2 and KNO 2 pure melts were determined by the time-of-flight neu-tron diffraction. The precise analyses of structural parameters obtained such as coordination number, interatomic distance, and temperature factor allowed us to conclude that (1) there exist stable NO2- anions in the melts, (2) NO2- anions behave like NO3- anions due to the existence of lone pairs of electrons, (3) the short-range structure of KNO2 pure melt is similar to that of NaNO2 pure melt but the cation site relative to anion is a little different from each other in terms of the cation size effect.

Original languageEnglish
Pages (from-to)741-744
Number of pages4
JournalElectrochemistry
Volume77
Issue number8
DOIs
Publication statusPublished - Aug 2009
Externally publishedYes

Keywords

  • KNO
  • Local structure
  • NaNO
  • Pulsed neutron diffraction
  • Pure melt

ASJC Scopus subject areas

  • Electrochemistry

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  • Cite this

    Iwadate, Y., Harada, T., Ohkubo, T., Fukushima, K., Misawa, M., Fukunaga, T., & Itoh, K. (2009). Pulsed neutron diffraction study of NaNO2 and KNO2 pure melts. Electrochemistry, 77(8), 741-744. https://doi.org/10.5796/electrochemistry.77.741