Pressure and temperature dependences of the structural properties of (formula presented) isomer I

Y. Takabayashi, Yoshihiro Kubozono, T. Kanbara, S. Fujiki, K. Shibata, Y. Haruyama, T. Hosokawa, Y. Rikiishi, S. Kashino

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Crystals of (formula presented) isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of (formula presented) shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

Original languageEnglish
Pages (from-to)1-4
Number of pages4
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume65
Issue number7
DOIs
Publication statusPublished - Jan 1 2002
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Pressure and temperature dependences of the structural properties of (formula presented) isomer I'. Together they form a unique fingerprint.

  • Cite this