Pressure and temperature dependences of the structural properties of Dy@C82 isomer I

Y. Takabayashi, Y. Kubozono, Yoshihiro Kubozono, S. Fujiki, K. Shibata, Y. Haruyama, T. Hosokawa, Y. Rikiishi, S. Kashino

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Crystals of Dy@C82 isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of Dy@C82 shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

Original languageEnglish
Article number073405
Pages (from-to)734051-734054
Number of pages4
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume65
Issue number7
Publication statusPublished - Feb 15 2002
Externally publishedYes

Fingerprint

Isomers
pressure dependence
Structural properties
isomers
temperature dependence
Lattice constants
Temperature
X rays
Synchrotron radiation
Equations of state
Differential scanning calorimetry
synchrotron radiation
x ray diffraction
equations of state
heat measurement
Diffraction
Phase transitions
Crystals
scanning
diffraction

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Takabayashi, Y., Kubozono, Y., Kubozono, Y., Fujiki, S., Shibata, K., Haruyama, Y., ... Kashino, S. (2002). Pressure and temperature dependences of the structural properties of Dy@C82 isomer I. Physical Review B - Condensed Matter and Materials Physics, 65(7), 734051-734054. [073405].

Pressure and temperature dependences of the structural properties of Dy@C82 isomer I. / Takabayashi, Y.; Kubozono, Y.; Kubozono, Yoshihiro; Fujiki, S.; Shibata, K.; Haruyama, Y.; Hosokawa, T.; Rikiishi, Y.; Kashino, S.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 65, No. 7, 073405, 15.02.2002, p. 734051-734054.

Research output: Contribution to journalArticle

Takabayashi, Y, Kubozono, Y, Kubozono, Y, Fujiki, S, Shibata, K, Haruyama, Y, Hosokawa, T, Rikiishi, Y & Kashino, S 2002, 'Pressure and temperature dependences of the structural properties of Dy@C82 isomer I', Physical Review B - Condensed Matter and Materials Physics, vol. 65, no. 7, 073405, pp. 734051-734054.
Takabayashi Y, Kubozono Y, Kubozono Y, Fujiki S, Shibata K, Haruyama Y et al. Pressure and temperature dependences of the structural properties of Dy@C82 isomer I. Physical Review B - Condensed Matter and Materials Physics. 2002 Feb 15;65(7):734051-734054. 073405.
Takabayashi, Y. ; Kubozono, Y. ; Kubozono, Yoshihiro ; Fujiki, S. ; Shibata, K. ; Haruyama, Y. ; Hosokawa, T. ; Rikiishi, Y. ; Kashino, S. / Pressure and temperature dependences of the structural properties of Dy@C82 isomer I. In: Physical Review B - Condensed Matter and Materials Physics. 2002 ; Vol. 65, No. 7. pp. 734051-734054.
@article{56bae8c0a5414f92aee9edad814c21ef,
title = "Pressure and temperature dependences of the structural properties of Dy@C82 isomer I",
abstract = "Crystals of Dy@C82 isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of Dy@C82 shows a simple cubic structure with lattice constant a of 15.85(3) {\AA} at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) {\AA}. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.",
author = "Y. Takabayashi and Y. Kubozono and Yoshihiro Kubozono and S. Fujiki and K. Shibata and Y. Haruyama and T. Hosokawa and Y. Rikiishi and S. Kashino",
year = "2002",
month = "2",
day = "15",
language = "English",
volume = "65",
pages = "734051--734054",
journal = "Physical Review B-Condensed Matter",
issn = "1098-0121",
publisher = "American Physical Society",
number = "7",

}

TY - JOUR

T1 - Pressure and temperature dependences of the structural properties of Dy@C82 isomer I

AU - Takabayashi, Y.

AU - Kubozono, Y.

AU - Kubozono, Yoshihiro

AU - Fujiki, S.

AU - Shibata, K.

AU - Haruyama, Y.

AU - Hosokawa, T.

AU - Rikiishi, Y.

AU - Kashino, S.

PY - 2002/2/15

Y1 - 2002/2/15

N2 - Crystals of Dy@C82 isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of Dy@C82 shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

AB - Crystals of Dy@C82 isomer I are studied by x-ray powder diffraction with synchrotron radiation in wide temperature and pressure regions. The isomer I of Dy@C82 shows a simple cubic structure with lattice constant a of 15.85(3) Å at 298 K, while the isomer II shows a face-centered cubic structure with a of 15.75(4) Å. The structural phase transition of the second order is indicated for the isomer I at 300-310 K by the temperature dependence of x-ray diffraction and differential scanning calorimetry. Further, the pressure dependence of the lattice constant is studied for the isomer I up to 60 kbar, which can be fitted by a Murnaghan equation of state.

UR - http://www.scopus.com/inward/record.url?scp=0141778110&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0141778110&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0141778110

VL - 65

SP - 734051

EP - 734054

JO - Physical Review B-Condensed Matter

JF - Physical Review B-Condensed Matter

SN - 1098-0121

IS - 7

M1 - 073405

ER -