Abstract
Mg-Al LDH intercalated PtCL4 2- anion (PtCl 4-LDH) was synthesized by a reconstruction method using potassium tetrachloroplatinate and its thermal changes were investigated at various temperatures. The PtCl4-LDH included 17 mass% Pt was synthesized by a reconstruction method using K2PtCl4 solution of 10 mM to adjust the pH with NaOH to about 11. The obtained PtCl4-LDH shows high crystallinity and has low content of CO3 2-. The basal spacing of the obtained PtCl4-LDH was 0.83 nm expanding slightly from 0.78 nm of starting LDH. The XRD patterns of the obtained PtCl 4-LDH showed that the second 001 diffraction line (006) became more accentuated than the first one (003) according to the intercalation of Pt components. Pt fine particles in the several nm were directly observed by TEM after firing at 500°C. However, the diffraction patterns of Pt or Pt components were not detected via XRD in the same sample. This is due to the coagulation of Pt components by the narrow basal spacing of the PtCl4-LDH.
| Original language | English |
|---|---|
| Pages (from-to) | 1229-1232 |
| Number of pages | 4 |
| Journal | Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan |
| Volume | 117 |
| Issue number | 1371 |
| Publication status | Published - Nov 2009 |
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Keywords
- Layered double hydroxide
- Nanocomposite
- Ptcl intercalation
- Thermal treatment
ASJC Scopus subject areas
- Ceramics and Composites
- Materials Chemistry
- Chemistry(all)
- Condensed Matter Physics
Cite this
Preparation of Pt particles dispersing nanocomposites by thermal treatment of tetrachloroplatinate/layered double hydroxide (LDH). / Kameshima, Yoshikazu; Nakajima, Akira; Okada, Kiyoshi; Yano, Toyohiko.
In: Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, Vol. 117, No. 1371, 11.2009, p. 1229-1232.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Preparation of Pt particles dispersing nanocomposites by thermal treatment of tetrachloroplatinate/layered double hydroxide (LDH)
AU - Kameshima, Yoshikazu
AU - Nakajima, Akira
AU - Okada, Kiyoshi
AU - Yano, Toyohiko
PY - 2009/11
Y1 - 2009/11
N2 - Mg-Al LDH intercalated PtCL4 2- anion (PtCl 4-LDH) was synthesized by a reconstruction method using potassium tetrachloroplatinate and its thermal changes were investigated at various temperatures. The PtCl4-LDH included 17 mass% Pt was synthesized by a reconstruction method using K2PtCl4 solution of 10 mM to adjust the pH with NaOH to about 11. The obtained PtCl4-LDH shows high crystallinity and has low content of CO3 2-. The basal spacing of the obtained PtCl4-LDH was 0.83 nm expanding slightly from 0.78 nm of starting LDH. The XRD patterns of the obtained PtCl 4-LDH showed that the second 001 diffraction line (006) became more accentuated than the first one (003) according to the intercalation of Pt components. Pt fine particles in the several nm were directly observed by TEM after firing at 500°C. However, the diffraction patterns of Pt or Pt components were not detected via XRD in the same sample. This is due to the coagulation of Pt components by the narrow basal spacing of the PtCl4-LDH.
AB - Mg-Al LDH intercalated PtCL4 2- anion (PtCl 4-LDH) was synthesized by a reconstruction method using potassium tetrachloroplatinate and its thermal changes were investigated at various temperatures. The PtCl4-LDH included 17 mass% Pt was synthesized by a reconstruction method using K2PtCl4 solution of 10 mM to adjust the pH with NaOH to about 11. The obtained PtCl4-LDH shows high crystallinity and has low content of CO3 2-. The basal spacing of the obtained PtCl4-LDH was 0.83 nm expanding slightly from 0.78 nm of starting LDH. The XRD patterns of the obtained PtCl 4-LDH showed that the second 001 diffraction line (006) became more accentuated than the first one (003) according to the intercalation of Pt components. Pt fine particles in the several nm were directly observed by TEM after firing at 500°C. However, the diffraction patterns of Pt or Pt components were not detected via XRD in the same sample. This is due to the coagulation of Pt components by the narrow basal spacing of the PtCl4-LDH.
KW - Layered double hydroxide
KW - Nanocomposite
KW - Ptcl intercalation
KW - Thermal treatment
UR - http://www.scopus.com/inward/record.url?scp=70449585622&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=70449585622&partnerID=8YFLogxK
M3 - Article
VL - 117
SP - 1229
EP - 1232
JO - Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
JF - Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
SN - 1882-0743
IS - 1371
ER -