Preparation of poly(ester-imide) ribbons comprised of helical and non-helical blocks by copolymerization

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Abstract

Helical ribbons of poly[4-(5-oxy-1,3-dioxoisoindoline-2-yl)benzoyl] (PODB) were previously prepared by the homo-polymerization of N-(4-carboxyphenyl)-4-acetoxyphthalimide (CAP) in aromatic solvents. The copolymerization of CAP and p-acetoxybenzoic acid (ABA) was examined to change the helical morphology. The helical morphology was extinguished by the copolymerization of a small amount of ABA at 280 °C at a concentration of 1.0% in aromatic solvent. Based on these results, ABA was added stepwise during the homo-polymerization of CAP. When a small amount of ABA was added, copolymer crystals comprised of helical and non-helical blocks were formed. The non-helical blocks grew on the PODB helical ribbons by the precipitation of co-oligomers. This result provides a novel method to control helical morphology by copolymerization.

Original languageEnglish
Pages (from-to)101995-102002
Number of pages8
JournalRSC Advances
Volume6
Issue number104
DOIs
Publication statusPublished - 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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