Preparation of iodo-induced 1,3-oxathiane compounds via intramolecular Pummerer rearrangement of 2-benzylsulfinyl- bicyclo[2.2.1]hept-5-ene

Hitoshi Abe, Hiroyuki Fujii, Natsuko Koshiba, Yasuo Takeuchi, Takashi Harayama

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Iodooxathianes (2a and 2b) were prepared from the γ,δ-unsaturated sulfinyl compound (1) via the iodonium-promoted intramolecular Pummerer reaction. A two-step conversion of 1 into 2a and 2b involving iodohydrination and the Pummerer rearrangement was also achieved.

Original languageEnglish
Pages (from-to)465-470
Number of pages6
JournalHeterocycles
Volume52
Issue number1
DOIs
Publication statusPublished - Jan 1 2000

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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