Preparation of a stable sulfonato-cobalt(III) complex by oxidation of a sulfinato-O complex

Mayumi Murata; Masaaki Kojima; Masakazu Kita; Setsuo Kashino; Yuzo Yoshikawa

doi:10.1246/cl.1996.675

Preparation of a stable sulfonato-cobalt(III) complex by oxidation of a sulfinato-O complex

Mayumi Murata, Masaaki Kojima, Masakazu Kita, Setsuo Kashino, Yuzo Yoshikawa

Research output: Contribution to journal › Article › peer-review

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Abstract

A stable sulfonato complex, [Co{OS(O)₂CH₂CH₂NH₂-O,N}(en) ₂]²⁺, was prepared upon oxidation of [Co{OS(O)-CH₂CH₂NH₂-O,N} (en)₂]²⁺ in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography (eluent: 0.1 mol dm^-3 Na₂[Sb₂{(+)-tartrate}₂]). The absolute configuration of the slower eluted (-)₅₈₉-isomer was determined to be Δ by the X-ray method.

Original language	English
Pages (from-to)	675-676
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1996.675
Publication status	Published - Jan 1 1996
Externally published	Yes

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Chemistry(all)

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title = "Preparation of a stable sulfonato-cobalt(III) complex by oxidation of a sulfinato-O complex",

abstract = "A stable sulfonato complex, [Co{OS(O)2CH2CH2NH2-O,N}(en) 2]2+, was prepared upon oxidation of [Co{OS(O)-CH2CH2NH2-O,N} (en)2]2+ in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography (eluent: 0.1 mol dm-3 Na2[Sb2{(+)-tartrate}2]). The absolute configuration of the slower eluted (-)589-isomer was determined to be Δ by the X-ray method.",

author = "Mayumi Murata and Masaaki Kojima and Masakazu Kita and Setsuo Kashino and Yuzo Yoshikawa",

year = "1996",

month = jan,

day = "1",

doi = "10.1246/cl.1996.675",

language = "English",

pages = "675--676",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "8",

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T1 - Preparation of a stable sulfonato-cobalt(III) complex by oxidation of a sulfinato-O complex

AU - Murata, Mayumi

AU - Kojima, Masaaki

AU - Kita, Masakazu

AU - Kashino, Setsuo

AU - Yoshikawa, Yuzo

PY - 1996/1/1

Y1 - 1996/1/1

N2 - A stable sulfonato complex, [Co{OS(O)2CH2CH2NH2-O,N}(en) 2]2+, was prepared upon oxidation of [Co{OS(O)-CH2CH2NH2-O,N} (en)2]2+ in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography (eluent: 0.1 mol dm-3 Na2[Sb2{(+)-tartrate}2]). The absolute configuration of the slower eluted (-)589-isomer was determined to be Δ by the X-ray method.

AB - A stable sulfonato complex, [Co{OS(O)2CH2CH2NH2-O,N}(en) 2]2+, was prepared upon oxidation of [Co{OS(O)-CH2CH2NH2-O,N} (en)2]2+ in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography (eluent: 0.1 mol dm-3 Na2[Sb2{(+)-tartrate}2]). The absolute configuration of the slower eluted (-)589-isomer was determined to be Δ by the X-ray method.

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DO - 10.1246/cl.1996.675

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EP - 676

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 8

ER -

Preparation of a stable sulfonato-cobalt(III) complex by oxidation of a sulfinato-O complex

Abstract

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