Abstract
A guest-sensitive chemiluminophore, a novel crown-ether-modified lophine peroxide 1, has been prepared, and its chemiluminescent behavior has been investigated in the presence of alkaline and alkaline earth metal cations. In the presence of Na+, the λmax of the chemiluminescence of peroxide 1 was blue-shifted (505 nm) compared to the case without a metal cation (566 nm). The chemiluminescent intensity was enhanced by addition of Na+ while that of Mg2+ decreased the intensity.
| Original language | English |
|---|---|
| Pages (from-to) | 7453-7455 |
| Number of pages | 3 |
| Journal | Tetrahedron Letters |
| Volume | 42 |
| Issue number | 42 |
| DOIs | |
| Publication status | Published - Oct 15 2001 |
Keywords
- Aza crown ether
- Chemiluminescence
- Chemiluminescent ionophore
- Lophine peroxide
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Okamoto, H., Owari, M., Kimura, M., & Satake, K. (2001). Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations. Tetrahedron Letters, 42(42), 7453-7455. https://doi.org/10.1016/S0040-4039(01)01572-6