Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations

Hideki Okamoto; Makoto Owari; Masaru Kimura; Kyosuke Satake

doi:10.1016/S0040-4039(01)01572-6

Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations

Hideki Okamoto, Makoto Owari, Masaru Kimura, Kyosuke Satake

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A guest-sensitive chemiluminophore, a novel crown-ether-modified lophine peroxide 1, has been prepared, and its chemiluminescent behavior has been investigated in the presence of alkaline and alkaline earth metal cations. In the presence of Na⁺, the λ_max of the chemiluminescence of peroxide 1 was blue-shifted (505 nm) compared to the case without a metal cation (566 nm). The chemiluminescent intensity was enhanced by addition of Na⁺ while that of Mg²⁺ decreased the intensity.

Original language	English
Pages (from-to)	7453-7455
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	42
DOIs	https://doi.org/10.1016/S0040-4039(01)01572-6
Publication status	Published - Oct 15 2001

Keywords

Aza crown ether
Chemiluminescence
Chemiluminescent ionophore
Lophine peroxide

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)01572-6

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title = "Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations",

abstract = "A guest-sensitive chemiluminophore, a novel crown-ether-modified lophine peroxide 1, has been prepared, and its chemiluminescent behavior has been investigated in the presence of alkaline and alkaline earth metal cations. In the presence of Na+, the λmax of the chemiluminescence of peroxide 1 was blue-shifted (505 nm) compared to the case without a metal cation (566 nm). The chemiluminescent intensity was enhanced by addition of Na+ while that of Mg2+ decreased the intensity.",

keywords = "Aza crown ether, Chemiluminescence, Chemiluminescent ionophore, Lophine peroxide",

author = "Hideki Okamoto and Makoto Owari and Masaru Kimura and Kyosuke Satake",

note = "Funding Information: This work was supported by a Grant-in-Aid (No. 13740398) from the Ministry of Education, Culture, Sports, Science and Technology of Japan. H.O. thanks Professor Dr. Waldemar Adam (University of W{\"u}rzburg) for active discussions and encouragement. The authors are grateful to the SC NMR Laboratory of Okayama University for the 500 MHz 1 H NMR measurements.",

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doi = "10.1016/S0040-4039(01)01572-6",

language = "English",

volume = "42",

pages = "7453--7455",

journal = "Tetrahedron Letters",

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T1 - Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations

AU - Okamoto, Hideki

AU - Owari, Makoto

AU - Kimura, Masaru

AU - Satake, Kyosuke

N1 - Funding Information: This work was supported by a Grant-in-Aid (No. 13740398) from the Ministry of Education, Culture, Sports, Science and Technology of Japan. H.O. thanks Professor Dr. Waldemar Adam (University of Würzburg) for active discussions and encouragement. The authors are grateful to the SC NMR Laboratory of Okayama University for the 500 MHz 1 H NMR measurements.

PY - 2001/10/15

Y1 - 2001/10/15

N2 - A guest-sensitive chemiluminophore, a novel crown-ether-modified lophine peroxide 1, has been prepared, and its chemiluminescent behavior has been investigated in the presence of alkaline and alkaline earth metal cations. In the presence of Na+, the λmax of the chemiluminescence of peroxide 1 was blue-shifted (505 nm) compared to the case without a metal cation (566 nm). The chemiluminescent intensity was enhanced by addition of Na+ while that of Mg2+ decreased the intensity.

AB - A guest-sensitive chemiluminophore, a novel crown-ether-modified lophine peroxide 1, has been prepared, and its chemiluminescent behavior has been investigated in the presence of alkaline and alkaline earth metal cations. In the presence of Na+, the λmax of the chemiluminescence of peroxide 1 was blue-shifted (505 nm) compared to the case without a metal cation (566 nm). The chemiluminescent intensity was enhanced by addition of Na+ while that of Mg2+ decreased the intensity.

KW - Aza crown ether

KW - Chemiluminescence

KW - Chemiluminescent ionophore

KW - Lophine peroxide

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DO - 10.1016/S0040-4039(01)01572-6

M3 - Article

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VL - 42

SP - 7453

EP - 7455

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 42

ER -

Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations

Abstract

Keywords

ASJC Scopus subject areas

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