Preparation of β-hetero-substituted alkenylsilanes from carboxylic acid derivatives

Kazuhiko Takai, Makoto Tezuka, Yasutaka Kataoka, Kiitiro Utimoto

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)


Esters are converted into β-alkoxy-substituted alkenylsilanes (7 examples) by means of the reagent prepared from dibromomethyltrimethylsilane, zinc, titanium(IV) chloride, and N,N,N',N'-tetramethylethylenediamine (TMEDA). β-Alkylthio-substituted alkenylsilanes (3 examples) are also produced from thioesters.

Original languageEnglish
Pages (from-to)27-28
Number of pages2
Issue number1
Publication statusPublished - Sep 1989
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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