Preparation of β-hetero-substituted alkenylsilanes from carboxylic acid derivatives

Kazuhiko Takai, Makoto Tezuka, Yasutaka Kataoka, Kiitiro Utimoto

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13 Citations (Scopus)

Abstract

Esters are converted into β-alkoxy-substituted alkenylsilanes (7 examples) by means of the reagent prepared from dibromomethyltrimethylsilane, zinc, titanium(IV) chloride, and N,N,N',N'-tetramethylethylenediamine (TMEDA). β-Alkylthio-substituted alkenylsilanes (3 examples) are also produced from thioesters.

Original languageEnglish
Pages (from-to)27-28
Number of pages2
JournalSynlett
Volume1989
Issue number1
DOIs
Publication statusPublished - Sep 1 1989
Externally publishedYes

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ASJC Scopus subject areas

  • Organic Chemistry

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