Preparation and solid acidity of zirconia-cluster/saponite composites

Yoshikazu Kameshima, Koji Kageyama, Yuuki Mizunuma, Takayuki Komatsu, Toshihiro Isobe, Akira Nakajima, Kiyoshi Okada

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Zirconia-cluster/saponite composites were prepared and evaluated as solid acid catalysts. The saponite layer was destructed in the composite through the dissolution of Al ion. The amount of zirconia-cluster in the composites was positively correlated with the Al amount, suggesting that zirconia-cluster inhibits the Al dissolution. Both the amounts of Brønsted and Lewis acids were increased by combining zirconia-cluster to saponite. Results show that Lewis acid on the saponite surface plays an important role on the entire catalytic activity on isomerization of 1-butene. The zirconia-cluster/saponite catalysts provided higher activity with a longer lifetime on this reaction than a commercial montmorillonite-based catalyst.

Original languageEnglish
Pages (from-to)49-53
Number of pages5
JournalJournal of the Ceramic Society of Japan
Volume121
Issue number1409
DOIs
Publication statusPublished - Jan 2013

Keywords

  • Catalyst
  • Isomerization
  • Saponite
  • Solid acidity
  • Zirconia cluster

ASJC Scopus subject areas

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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    Kameshima, Y., Kageyama, K., Mizunuma, Y., Komatsu, T., Isobe, T., Nakajima, A., & Okada, K. (2013). Preparation and solid acidity of zirconia-cluster/saponite composites. Journal of the Ceramic Society of Japan, 121(1409), 49-53. https://doi.org/10.2109/jcersj2.121.49