Abstract
Four o-xylylene groups of phthalocyanine (2) were removed by Birch reduction and the generated octathiolate anions were then reacted with Se to give tetrakis(dithiaselenolo)phthalocyanine (3). The dication generated from 3 in CHCl3/TFA was determined with UV-vis and NMR spectroscopy.
Original language | English |
---|---|
Pages (from-to) | 1081-1086 |
Number of pages | 6 |
Journal | Heterocycles |
Volume | 79 |
Issue number | C |
DOIs | |
Publication status | Published - 2009 |
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Keywords
- Dithiaselenole Ring
- NMR Spectra
- Phthalocyanine
- Protonation
- UV-Vis Spectra
ASJC Scopus subject areas
- Analytical Chemistry
- Organic Chemistry
- Pharmacology
Cite this
Preparation and electrochemical and optical properties of tetrakis(dithiaselenolo)phthalocyanine. / Kimura, Takeshi; Namauo, Toshiharu; Yamakawa, Akio; Takaguchi, Yutaka.
In: Heterocycles, Vol. 79, No. C, 2009, p. 1081-1086.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Preparation and electrochemical and optical properties of tetrakis(dithiaselenolo)phthalocyanine
AU - Kimura, Takeshi
AU - Namauo, Toshiharu
AU - Yamakawa, Akio
AU - Takaguchi, Yutaka
PY - 2009
Y1 - 2009
N2 - Four o-xylylene groups of phthalocyanine (2) were removed by Birch reduction and the generated octathiolate anions were then reacted with Se to give tetrakis(dithiaselenolo)phthalocyanine (3). The dication generated from 3 in CHCl3/TFA was determined with UV-vis and NMR spectroscopy.
AB - Four o-xylylene groups of phthalocyanine (2) were removed by Birch reduction and the generated octathiolate anions were then reacted with Se to give tetrakis(dithiaselenolo)phthalocyanine (3). The dication generated from 3 in CHCl3/TFA was determined with UV-vis and NMR spectroscopy.
KW - Dithiaselenole Ring
KW - NMR Spectra
KW - Phthalocyanine
KW - Protonation
KW - UV-Vis Spectra
UR - http://www.scopus.com/inward/record.url?scp=67651159156&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67651159156&partnerID=8YFLogxK
U2 - 10.3987/COM-08-S(D)27
DO - 10.3987/COM-08-S(D)27
M3 - Article
AN - SCOPUS:67651159156
VL - 79
SP - 1081
EP - 1086
JO - Heterocycles
JF - Heterocycles
SN - 0385-5414
IS - C
ER -