TY - JOUR
T1 - Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges
AU - Vanthoeun, Keo
AU - Bunho, Toh
AU - Mitsuhashi, Ryoji
AU - Suzuki, Takayoshi
AU - Kita, Masakazu
N1 - Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2013/1/1
Y1 - 2013/1/1
N2 - New metal complexes with N,N-diacetatodithiocarbamate (Ac 2dtc3-), Na6[Co(Ac2dtc) 3], Ba3[Co(Ac2dtc)3], Na 4[Ni(Ac2dtc)2], Ba2[Ni(Ac 2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc) 3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.
AB - New metal complexes with N,N-diacetatodithiocarbamate (Ac 2dtc3-), Na6[Co(Ac2dtc) 3], Ba3[Co(Ac2dtc)3], Na 4[Ni(Ac2dtc)2], Ba2[Ni(Ac 2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc) 3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.
KW - Crystal structure
KW - Dithiocarbamato complex
KW - Large negative charge
KW - Network structure
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U2 - 10.1016/j.ica.2012.08.028
DO - 10.1016/j.ica.2012.08.028
M3 - Article
AN - SCOPUS:84867312689
VL - 394
SP - 410
EP - 414
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -