Abstract
New metal complexes with N,N-diacetatodithiocarbamate (Ac 2dtc3-), Na6[Co(Ac2dtc) 3], Ba3[Co(Ac2dtc)3], Na 4[Ni(Ac2dtc)2], Ba2[Ni(Ac 2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc) 3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.
Original language | English |
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Pages (from-to) | 410-414 |
Number of pages | 5 |
Journal | Inorganica Chimica Acta |
Volume | 394 |
DOIs | |
Publication status | Published - Jan 1 2013 |
Keywords
- Crystal structure
- Dithiocarbamato complex
- Large negative charge
- Network structure
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry