Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges

Keo Vanthoeun; Toh Bunho; Ryoji Mitsuhashi; Takayoshi Suzuki; Masakazu Kita

doi:10.1016/j.ica.2012.08.028

Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges

Keo Vanthoeun, Toh Bunho, Ryoji Mitsuhashi, Takayoshi Suzuki, Masakazu Kita

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

New metal complexes with N,N-diacetatodithiocarbamate (Ac ₂dtc^3-), Na₆[Co(Ac₂dtc) ₃], Ba₃[Co(Ac₂dtc)₃], Na ₄[Ni(Ac₂dtc)₂], Ba₂[Ni(Ac ₂dtc)₂], Na₄[Cu(Ac₂dtc)₂] and Ba₂[Cu(Ac₂dtc)₂], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba₃[Co(Ac₂dtc) ₃]·16H₂O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.

Original language	English
Pages (from-to)	410-414
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	394
DOIs	https://doi.org/10.1016/j.ica.2012.08.028
Publication status	Published - Jan 1 2013

Keywords

Crystal structure
Dithiocarbamato complex
Large negative charge
Network structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Vanthoeun, K., Bunho, T., Mitsuhashi, R., Suzuki, T., & Kita, M. (2013). Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges. Inorganica Chimica Acta, 394, 410-414. https://doi.org/10.1016/j.ica.2012.08.028

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title = "Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges",

abstract = "New metal complexes with N,N-diacetatodithiocarbamate (Ac 2dtc3-), Na6[Co(Ac2dtc) 3], Ba3[Co(Ac2dtc)3], Na 4[Ni(Ac2dtc)2], Ba2[Ni(Ac 2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc) 3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.",

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author = "Keo Vanthoeun and Toh Bunho and Ryoji Mitsuhashi and Takayoshi Suzuki and Masakazu Kita",

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T1 - Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges

AU - Vanthoeun, Keo

AU - Bunho, Toh

AU - Mitsuhashi, Ryoji

AU - Suzuki, Takayoshi

AU - Kita, Masakazu

PY - 2013/1/1

Y1 - 2013/1/1

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AB - New metal complexes with N,N-diacetatodithiocarbamate (Ac 2dtc3-), Na6[Co(Ac2dtc) 3], Ba3[Co(Ac2dtc)3], Na 4[Ni(Ac2dtc)2], Ba2[Ni(Ac 2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc) 3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.

KW - Crystal structure

KW - Dithiocarbamato complex

KW - Large negative charge

KW - Network structure

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