Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges

Keo Vanthoeun, Toh Bunho, Ryoji Mitsuhashi, Takayoshi Suzuki, Masakazu Kita

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

New metal complexes with N,N-diacetatodithiocarbamate (Ac 2dtc3-), Na6[Co(Ac2dtc) 3], Ba3[Co(Ac2dtc)3], Na 4[Ni(Ac2dtc)2], Ba2[Ni(Ac 2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc) 3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.

Original languageEnglish
Pages (from-to)410-414
Number of pages5
JournalInorganica Chimica Acta
Volume394
DOIs
Publication statusPublished - Jan 1 2013

Keywords

  • Crystal structure
  • Dithiocarbamato complex
  • Large negative charge
  • Network structure

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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