Preparation and characterization of bis(cyclopentadienyl)zirconium(II) complexes with a tethered olefin-phosphine ligand

Akiko Yamazaki; Yasushi Nishihara; Kiyohiko Nakajima; Ryuichiro Hara; Tamotsu Takahashi

doi:10.1021/om990103u

Preparation and characterization of bis(cyclopentadienyl)zirconium(II) complexes with a tethered olefin-phosphine ligand

Akiko Yamazaki, Yasushi Nishihara, Kiyohiko Nakajima, Ryuichiro Hara, Tamotsu Takahashi

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Unprecedented zirconium(II) complexes bearing tethered olefin - phosphine ligands were synthesized and characterized. The molecular structures of the newly synthesized complexes (η⁵-1,2-Me₂C₅H₃) ₂Zr(CH₂=CHCH₂CH₂PPh₂) (1c) and Cp₂Zr(CH₂=CHCH₂CH₂CH ₂PPh₂) (2a) were determined by single-crystal X-ray diffraction methods. The stability and reactivity of the series of complexes Cp₂Zr{CH₂=CH(CH₂)_nPR₂} (n = 2, 3; R = Et, Ph) were examined. The complex 2a showed simultaneously both sufficient stability and high reactivity.

Original language	English
Pages (from-to)	3105-3108
Number of pages	4
Journal	Organometallics
Volume	18
Issue number	16
DOIs	https://doi.org/10.1021/om990103u
Publication status	Published - Aug 2 1999
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Preparation and characterization of bis(cyclopentadienyl)zirconium(II) complexes with a tethered olefin-phosphine ligand",

abstract = "Unprecedented zirconium(II) complexes bearing tethered olefin - phosphine ligands were synthesized and characterized. The molecular structures of the newly synthesized complexes (η5-1,2-Me2C5H3) 2Zr(CH2=CHCH2CH2PPh2) (1c) and Cp2Zr(CH2=CHCH2CH2CH 2PPh2) (2a) were determined by single-crystal X-ray diffraction methods. The stability and reactivity of the series of complexes Cp2Zr{CH2=CH(CH2)nPR2} (n = 2, 3; R = Et, Ph) were examined. The complex 2a showed simultaneously both sufficient stability and high reactivity.",

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year = "1999",

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T1 - Preparation and characterization of bis(cyclopentadienyl)zirconium(II) complexes with a tethered olefin-phosphine ligand

AU - Yamazaki, Akiko

AU - Nishihara, Yasushi

AU - Nakajima, Kiyohiko

AU - Hara, Ryuichiro

AU - Takahashi, Tamotsu

PY - 1999/8/2

Y1 - 1999/8/2

N2 - Unprecedented zirconium(II) complexes bearing tethered olefin - phosphine ligands were synthesized and characterized. The molecular structures of the newly synthesized complexes (η5-1,2-Me2C5H3) 2Zr(CH2=CHCH2CH2PPh2) (1c) and Cp2Zr(CH2=CHCH2CH2CH 2PPh2) (2a) were determined by single-crystal X-ray diffraction methods. The stability and reactivity of the series of complexes Cp2Zr{CH2=CH(CH2)nPR2} (n = 2, 3; R = Et, Ph) were examined. The complex 2a showed simultaneously both sufficient stability and high reactivity.

AB - Unprecedented zirconium(II) complexes bearing tethered olefin - phosphine ligands were synthesized and characterized. The molecular structures of the newly synthesized complexes (η5-1,2-Me2C5H3) 2Zr(CH2=CHCH2CH2PPh2) (1c) and Cp2Zr(CH2=CHCH2CH2CH 2PPh2) (2a) were determined by single-crystal X-ray diffraction methods. The stability and reactivity of the series of complexes Cp2Zr{CH2=CH(CH2)nPR2} (n = 2, 3; R = Et, Ph) were examined. The complex 2a showed simultaneously both sufficient stability and high reactivity.

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