Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

Hisashi Fujihara; Yutaka Takaguchi; Takeshi Ninoi; Tomoki Erata; Naomichi Furukawa

doi:10.1039/p19920002583

Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

Hisashi Fujihara, Yutaka Takaguchi, Takeshi Ninoi, Tomoki Erata, Naomichi Furukawa

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

1,5-Ditelluracyclooctane 1 reacted with halogens (I₂ and Cl₂) to give new dihalogenoditelluranes with a Te^IV-Te^IV. Reduction of the latter with aqueous NaOH, PhSH, Na₂S and SmI₂ gave the neutral bis-telluride 1.

Original language	English
Pages (from-to)	2583-2584
Number of pages	2
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	20
DOIs	https://doi.org/10.1039/p19920002583
Publication status	Published - 1992
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/p19920002583

Cite this

Fujihara, H., Takaguchi, Y., Ninoi, T., Erata, T., & Furukawa, N. (1992). Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species. Journal of the Chemical Society, Perkin Transactions 1, (20), 2583-2584. https://doi.org/10.1039/p19920002583

Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane : A new multicentre hypervalent species. / Fujihara, Hisashi; Takaguchi, Yutaka; Ninoi, Takeshi; Erata, Tomoki; Furukawa, Naomichi.

In: Journal of the Chemical Society, Perkin Transactions 1, No. 20, 1992, p. 2583-2584.

Research output: Contribution to journal › Article › peer-review

Fujihara, H, Takaguchi, Y, Ninoi, T, Erata, T & Furukawa, N 1992, 'Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species', Journal of the Chemical Society, Perkin Transactions 1, no. 20, pp. 2583-2584. https://doi.org/10.1039/p19920002583

Fujihara, Hisashi ; Takaguchi, Yutaka ; Ninoi, Takeshi ; Erata, Tomoki ; Furukawa, Naomichi. / Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane : A new multicentre hypervalent species. In: Journal of the Chemical Society, Perkin Transactions 1. 1992 ; No. 20. pp. 2583-2584.

@article{79db7871329048e99a1518dddba56cf6,

title = "Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species",

abstract = "1,5-Ditelluracyclooctane 1 reacted with halogens (I2 and Cl2) to give new dihalogenoditelluranes with a TeIV-TeIV. Reduction of the latter with aqueous NaOH, PhSH, Na2S and SmI2 gave the neutral bis-telluride 1.",

author = "Hisashi Fujihara and Yutaka Takaguchi and Takeshi Ninoi and Tomoki Erata and Naomichi Furukawa",

year = "1992",

doi = "10.1039/p19920002583",

language = "English",

pages = "2583--2584",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "1472-7781",

publisher = "Chemical Society",

number = "20",

}

TY - JOUR

T1 - Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane

T2 - A new multicentre hypervalent species

AU - Fujihara, Hisashi

AU - Takaguchi, Yutaka

AU - Ninoi, Takeshi

AU - Erata, Tomoki

AU - Furukawa, Naomichi

PY - 1992

Y1 - 1992

N2 - 1,5-Ditelluracyclooctane 1 reacted with halogens (I2 and Cl2) to give new dihalogenoditelluranes with a TeIV-TeIV. Reduction of the latter with aqueous NaOH, PhSH, Na2S and SmI2 gave the neutral bis-telluride 1.

AB - 1,5-Ditelluracyclooctane 1 reacted with halogens (I2 and Cl2) to give new dihalogenoditelluranes with a TeIV-TeIV. Reduction of the latter with aqueous NaOH, PhSH, Na2S and SmI2 gave the neutral bis-telluride 1.

UR - http://www.scopus.com/inward/record.url?scp=37049071170&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049071170&partnerID=8YFLogxK

U2 - 10.1039/p19920002583

DO - 10.1039/p19920002583

M3 - Article

AN - SCOPUS:37049071170

SP - 2583

EP - 2584

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

SN - 1472-7781

IS - 20

ER -

Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this