Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

Hisashi Fujihara; Yutaka Takaguchi; Takeshi Ninoi; Tomoki Erata; Naomichi Furukawa

doi:10.1039/p19920002583

Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

Hisashi Fujihara, Yutaka Takaguchi, Takeshi Ninoi, Tomoki Erata, Naomichi Furukawa

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

1,5-Ditelluracyclooctane 1 reacted with halogens (I₂ and Cl₂) to give new dihalogenoditelluranes with a Te^IV-Te^IV. Reduction of the latter with aqueous NaOH, PhSH, Na₂S and SmI₂ gave the neutral bis-telluride 1.

Original language	English
Pages (from-to)	2583-2584
Number of pages	2
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	20
DOIs	https://doi.org/10.1039/p19920002583
Publication status	Published - 1992
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Fujihara, H., Takaguchi, Y., Ninoi, T., Erata, T., & Furukawa, N. (1992). Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species. Journal of the Chemical Society, Perkin Transactions 1, (20), 2583-2584. https://doi.org/10.1039/p19920002583

Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane : A new multicentre hypervalent species. / Fujihara, Hisashi; Takaguchi, Yutaka; Ninoi, Takeshi et al.

In: Journal of the Chemical Society, Perkin Transactions 1, No. 20, 1992, p. 2583-2584.

Research output: Contribution to journal › Article › peer-review

Fujihara, H, Takaguchi, Y, Ninoi, T, Erata, T & Furukawa, N 1992, 'Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species', Journal of the Chemical Society, Perkin Transactions 1, no. 20, pp. 2583-2584. https://doi.org/10.1039/p19920002583

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abstract = "1,5-Ditelluracyclooctane 1 reacted with halogens (I2 and Cl2) to give new dihalogenoditelluranes with a TeIV-TeIV. Reduction of the latter with aqueous NaOH, PhSH, Na2S and SmI2 gave the neutral bis-telluride 1.",

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AU - Ninoi, Takeshi

AU - Erata, Tomoki

AU - Furukawa, Naomichi

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Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

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