Polypeptide and Mn-Ca oxide: Toward a biomimetic catalyst for water-splitting systems

Mohammad Mahdi Najafpour, Mohadeseh Zarei Ghobadi, Bahram Sarvi, Sepideh Madadkhani, Davood Jafarian Sedigh, Parvin Rafighi, Mojtaba Tavahodi, Jian Ren Shen, Suleyman I. Allakhverdiev

    Research output: Contribution to journalArticlepeer-review

    22 Citations (Scopus)

    Abstract

    Water oxidation is the bottleneck for hydrogen production by water-splitting systems using sunlight or other sustainable energies. Herein we report nano-sized Mn-Ca oxide in an engineered polypeptide (Glu-Glu-Glu-Glu-Glu-Glu-Glu-His-Val-Val-Val-Val-Val-Val-Val-Val) as a structural model for biological water-oxidizing site in plants, algae, and cyanobacteria. The compound was synthesized by a simple procedure and characterized by transmission electron microscopy, atomic absorption spectroscopy, scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction spectrometry, UV-Visible spectroscopy, dynamic light scattering, and some electrochemical methods. Using hydrogen to store sustainable energies is a promising strategy in near future and such nano-sized Mn-Ca oxide/polypeptide is a promising strategy in water-splitting systems to provide cheap electrons from water toward hydrogen production.

    Original languageEnglish
    Pages (from-to)5504-5512
    Number of pages9
    JournalInternational Journal of Hydrogen Energy
    Volume41
    Issue number12
    DOIs
    Publication statusPublished - Apr 6 2016

    Keywords

    • Biomimetic model
    • Hydrogen
    • Nano-sized Mn-Ca oxide
    • Polypeptide
    • Water-oxidizing catalyst

    ASJC Scopus subject areas

    • Renewable Energy, Sustainability and the Environment
    • Fuel Technology
    • Condensed Matter Physics
    • Energy Engineering and Power Technology

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