Abstract
Polymerization and depolymerization of C60 molecules are induced by charge carrier injection from a scanning tunneling microscope tip into C60 close-packed layers. These reactions are hard to be achieved at single molecular precision because of a spatial spread of injected carriers. We report that the carrier-spreading effect produces a ring-shaped distribution of C60 polymers around the carrier injection point. Formation of the polymer ring of C60 is explained by energy dissipation of spreading carriers. Therefore, the polymer ring can be recognized as a direct reflection of carrier propagation. Subsequent electron or hole injections enlarge the ring. This result shows that both electrons and holes can induce both polymerization and depolymerization of C60 molecules.
| Original language | English |
|---|---|
| Pages (from-to) | 3017-3020 |
| Number of pages | 4 |
| Journal | Physica Status Solidi (B) Basic Research |
| Volume | 243 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Nov 2006 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Electronic, Optical and Magnetic Materials
Cite this
Polymer ring formation by electron/hole injection from an STM tip into a C60 close-packed layer. / Nouchi, Ryo; Masunari, Kosuke; Ohta, Toshio; Kubozono, Yoshihiro; Iwasa, Yoshihiro.
In: Physica Status Solidi (B) Basic Research, Vol. 243, No. 13, 11.2006, p. 3017-3020.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Polymer ring formation by electron/hole injection from an STM tip into a C60 close-packed layer
AU - Nouchi, Ryo
AU - Masunari, Kosuke
AU - Ohta, Toshio
AU - Kubozono, Yoshihiro
AU - Iwasa, Yoshihiro
PY - 2006/11
Y1 - 2006/11
N2 - Polymerization and depolymerization of C60 molecules are induced by charge carrier injection from a scanning tunneling microscope tip into C60 close-packed layers. These reactions are hard to be achieved at single molecular precision because of a spatial spread of injected carriers. We report that the carrier-spreading effect produces a ring-shaped distribution of C60 polymers around the carrier injection point. Formation of the polymer ring of C60 is explained by energy dissipation of spreading carriers. Therefore, the polymer ring can be recognized as a direct reflection of carrier propagation. Subsequent electron or hole injections enlarge the ring. This result shows that both electrons and holes can induce both polymerization and depolymerization of C60 molecules.
AB - Polymerization and depolymerization of C60 molecules are induced by charge carrier injection from a scanning tunneling microscope tip into C60 close-packed layers. These reactions are hard to be achieved at single molecular precision because of a spatial spread of injected carriers. We report that the carrier-spreading effect produces a ring-shaped distribution of C60 polymers around the carrier injection point. Formation of the polymer ring of C60 is explained by energy dissipation of spreading carriers. Therefore, the polymer ring can be recognized as a direct reflection of carrier propagation. Subsequent electron or hole injections enlarge the ring. This result shows that both electrons and holes can induce both polymerization and depolymerization of C60 molecules.
UR - http://www.scopus.com/inward/record.url?scp=33751258594&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33751258594&partnerID=8YFLogxK
U2 - 10.1002/pssb.200669154
DO - 10.1002/pssb.200669154
M3 - Article
AN - SCOPUS:33751258594
VL - 243
SP - 3017
EP - 3020
JO - Physica Status Solidi (B): Basic Research
JF - Physica Status Solidi (B): Basic Research
SN - 0370-1972
IS - 13
ER -