Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group

Jiro Tanaka, Toshiaki Hashimoto, Jeffrey W. Stansbury, Joseph M. Antonucci, Kazuomi Suzuki

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The properties of dental matrix resins have been improved by synthesis of new monomers. However, except for improvements in water-resistance, monomers with better mechanical properties than Bis-GMA and UDMA could not being synthesized. Changing the point of emphasis, we tried to improve the mechanical properties controlling the matrix resin higher structure using noncovalent bonds. We prepared a matrix resin structured by UDMA, which is a high viscosity base monomer with imino groups, and by a low viscosity acidic monomer with carboxyl groups, which permits noncovalent bonds such as hydrogen bonds or electrostatic interaction with imino groups. The maximal mechanical strength for matrix resins structured by UDMA and an acidic monomer was obtained with a composition of imino groups and carboxyl groups at a ratio of 1:1. This mechanical strength value was higher than those obtained with UDMA resin or with a Bis-GMA/TEGDMA/UDMA resin with typical composition. The improvement in mechanical properties may be due to the complex based on noncovalent bonds, between the imino groups of UDMA and the carboxyl groups of the acidic monomers.

Original languageEnglish
Pages (from-to)206-215
Number of pages10
JournalDental Materials Journal
Volume20
Issue number3
Publication statusPublished - Sep 2001

Fingerprint

Bisphenol A-Glycidyl Methacrylate
Methacrylates
Viscosity
Polymers
Resins
Monomers
Synthetic Resins
Static Electricity
Hydrogen
Mechanical properties
Strength of materials
Water
Coulomb interactions
Chemical analysis
Hydrogen bonds

Keywords

  • Cross-linked structure
  • Electrostatic interaction
  • Hydrogen bond

ASJC Scopus subject areas

  • Dentistry(all)
  • Biomaterials

Cite this

Tanaka, J., Hashimoto, T., Stansbury, J. W., Antonucci, J. M., & Suzuki, K. (2001). Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group. Dental Materials Journal, 20(3), 206-215.

Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group. / Tanaka, Jiro; Hashimoto, Toshiaki; Stansbury, Jeffrey W.; Antonucci, Joseph M.; Suzuki, Kazuomi.

In: Dental Materials Journal, Vol. 20, No. 3, 09.2001, p. 206-215.

Research output: Contribution to journalArticle

Tanaka, J, Hashimoto, T, Stansbury, JW, Antonucci, JM & Suzuki, K 2001, 'Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group', Dental Materials Journal, vol. 20, no. 3, pp. 206-215.
Tanaka J, Hashimoto T, Stansbury JW, Antonucci JM, Suzuki K. Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group. Dental Materials Journal. 2001 Sep;20(3):206-215.
Tanaka, Jiro ; Hashimoto, Toshiaki ; Stansbury, Jeffrey W. ; Antonucci, Joseph M. ; Suzuki, Kazuomi. / Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group. In: Dental Materials Journal. 2001 ; Vol. 20, No. 3. pp. 206-215.
@article{7452bc230158472b810b15d5b9b3da21,
title = "Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group",
abstract = "The properties of dental matrix resins have been improved by synthesis of new monomers. However, except for improvements in water-resistance, monomers with better mechanical properties than Bis-GMA and UDMA could not being synthesized. Changing the point of emphasis, we tried to improve the mechanical properties controlling the matrix resin higher structure using noncovalent bonds. We prepared a matrix resin structured by UDMA, which is a high viscosity base monomer with imino groups, and by a low viscosity acidic monomer with carboxyl groups, which permits noncovalent bonds such as hydrogen bonds or electrostatic interaction with imino groups. The maximal mechanical strength for matrix resins structured by UDMA and an acidic monomer was obtained with a composition of imino groups and carboxyl groups at a ratio of 1:1. This mechanical strength value was higher than those obtained with UDMA resin or with a Bis-GMA/TEGDMA/UDMA resin with typical composition. The improvement in mechanical properties may be due to the complex based on noncovalent bonds, between the imino groups of UDMA and the carboxyl groups of the acidic monomers.",
keywords = "Cross-linked structure, Electrostatic interaction, Hydrogen bond",
author = "Jiro Tanaka and Toshiaki Hashimoto and Stansbury, {Jeffrey W.} and Antonucci, {Joseph M.} and Kazuomi Suzuki",
year = "2001",
month = "9",
language = "English",
volume = "20",
pages = "206--215",
journal = "Dental Materials Journal",
issn = "0287-4547",
publisher = "Japanese Society for Dental Materials and Devices",
number = "3",

}

TY - JOUR

T1 - Polymer Properties on Resins composed of UDMA and Methacrylates with the Carboxyl Group

AU - Tanaka, Jiro

AU - Hashimoto, Toshiaki

AU - Stansbury, Jeffrey W.

AU - Antonucci, Joseph M.

AU - Suzuki, Kazuomi

PY - 2001/9

Y1 - 2001/9

N2 - The properties of dental matrix resins have been improved by synthesis of new monomers. However, except for improvements in water-resistance, monomers with better mechanical properties than Bis-GMA and UDMA could not being synthesized. Changing the point of emphasis, we tried to improve the mechanical properties controlling the matrix resin higher structure using noncovalent bonds. We prepared a matrix resin structured by UDMA, which is a high viscosity base monomer with imino groups, and by a low viscosity acidic monomer with carboxyl groups, which permits noncovalent bonds such as hydrogen bonds or electrostatic interaction with imino groups. The maximal mechanical strength for matrix resins structured by UDMA and an acidic monomer was obtained with a composition of imino groups and carboxyl groups at a ratio of 1:1. This mechanical strength value was higher than those obtained with UDMA resin or with a Bis-GMA/TEGDMA/UDMA resin with typical composition. The improvement in mechanical properties may be due to the complex based on noncovalent bonds, between the imino groups of UDMA and the carboxyl groups of the acidic monomers.

AB - The properties of dental matrix resins have been improved by synthesis of new monomers. However, except for improvements in water-resistance, monomers with better mechanical properties than Bis-GMA and UDMA could not being synthesized. Changing the point of emphasis, we tried to improve the mechanical properties controlling the matrix resin higher structure using noncovalent bonds. We prepared a matrix resin structured by UDMA, which is a high viscosity base monomer with imino groups, and by a low viscosity acidic monomer with carboxyl groups, which permits noncovalent bonds such as hydrogen bonds or electrostatic interaction with imino groups. The maximal mechanical strength for matrix resins structured by UDMA and an acidic monomer was obtained with a composition of imino groups and carboxyl groups at a ratio of 1:1. This mechanical strength value was higher than those obtained with UDMA resin or with a Bis-GMA/TEGDMA/UDMA resin with typical composition. The improvement in mechanical properties may be due to the complex based on noncovalent bonds, between the imino groups of UDMA and the carboxyl groups of the acidic monomers.

KW - Cross-linked structure

KW - Electrostatic interaction

KW - Hydrogen bond

UR - http://www.scopus.com/inward/record.url?scp=0035468386&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035468386&partnerID=8YFLogxK

M3 - Article

C2 - 11806155

AN - SCOPUS:0035468386

VL - 20

SP - 206

EP - 215

JO - Dental Materials Journal

JF - Dental Materials Journal

SN - 0287-4547

IS - 3

ER -