TY - JOUR
T1 - Poly[(μ4-chloranilato)bis-(saccharin)disodium(I)]
AU - Refat, Moamen S.
AU - Hashem, Hassan A.
AU - Gotoh, Kazuma
AU - Ishida, Hiroyuki
PY - 2007
Y1 - 2007
N2 - In the title compound {systematic name: poly[(4-2,5-dichloro-3,6-dihydr- oxy-1,4-benzoquinona-to)bis-[1,2-benzisothia-zol-3(2H)-one 1,1-dioxide] disodium(I)]}, [Na2(C6Cl2O4)(C7H5NO3S)2] n , the NaI atom is coordinated by six O atoms from three chloranilate ions and two saccharin ligands in a distorted octa-hedral geometry. There is an intra-molecular N - H⋯O hydrogen bond between the saccharin ligand and the chloranilate dianion. Each O atom of the chloranilate ion bonds to two NaI atoms, while the saccharin ligand bridges the NaI atoms via the carbonyl O atom and one of the sulfonyl O atoms. The Na atoms and bridging ligands form layers parallel to the ab plane at z = 0 and z = . The shortest Na⋯Na and Na⋯Cl distances in the layer are 3.6006 (12) and 3.0680 (7) Å, respectively.
AB - In the title compound {systematic name: poly[(4-2,5-dichloro-3,6-dihydr- oxy-1,4-benzoquinona-to)bis-[1,2-benzisothia-zol-3(2H)-one 1,1-dioxide] disodium(I)]}, [Na2(C6Cl2O4)(C7H5NO3S)2] n , the NaI atom is coordinated by six O atoms from three chloranilate ions and two saccharin ligands in a distorted octa-hedral geometry. There is an intra-molecular N - H⋯O hydrogen bond between the saccharin ligand and the chloranilate dianion. Each O atom of the chloranilate ion bonds to two NaI atoms, while the saccharin ligand bridges the NaI atoms via the carbonyl O atom and one of the sulfonyl O atoms. The Na atoms and bridging ligands form layers parallel to the ab plane at z = 0 and z = . The shortest Na⋯Na and Na⋯Cl distances in the layer are 3.6006 (12) and 3.0680 (7) Å, respectively.
UR - http://www.scopus.com/inward/record.url?scp=57349144352&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=57349144352&partnerID=8YFLogxK
U2 - 10.1107/S1600536807016728
DO - 10.1107/S1600536807016728
M3 - Article
AN - SCOPUS:57349144352
VL - 63
SP - m1383-m1384
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 5
ER -