Poly[(μ4-chloranilato)bis-(saccharin)disodium(I)]

Moamen S. Refat, Hassan A. Hashem, Kazuma Gotoh, Hiroyuki Ishida

Research output: Contribution to journalArticle

Abstract

In the title compound {systematic name: poly[(4-2,5-dichloro-3,6-dihydr- oxy-1,4-benzoquinona-to)bis-[1,2-benzisothia-zol-3(2H)-one 1,1-dioxide] disodium(I)]}, [Na2(C6Cl2O4)(C7H5NO3S)2] n , the NaI atom is coordinated by six O atoms from three chloranilate ions and two saccharin ligands in a distorted octa-hedral geometry. There is an intra-molecular N - H⋯O hydrogen bond between the saccharin ligand and the chloranilate dianion. Each O atom of the chloranilate ion bonds to two NaI atoms, while the saccharin ligand bridges the NaI atoms via the carbonyl O atom and one of the sulfonyl O atoms. The Na atoms and bridging ligands form layers parallel to the ab plane at z = 0 and z = . The shortest Na⋯Na and Na⋯Cl distances in the layer are 3.6006 (12) and 3.0680 (7) Å, respectively.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number5
DOIs
Publication statusPublished - 2007

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Saccharin
Atoms
atoms
Ligands
ligands
Ions
dioxides
Hydrogen bonds
ions
hydrogen bonds
Geometry

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Poly[(μ4-chloranilato)bis-(saccharin)disodium(I)]. / Refat, Moamen S.; Hashem, Hassan A.; Gotoh, Kazuma; Ishida, Hiroyuki.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 5, 2007.

Research output: Contribution to journalArticle

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abstract = "In the title compound {systematic name: poly[(4-2,5-dichloro-3,6-dihydr- oxy-1,4-benzoquinona-to)bis-[1,2-benzisothia-zol-3(2H)-one 1,1-dioxide] disodium(I)]}, [Na2(C6Cl2O4)(C7H5NO3S)2] n , the NaI atom is coordinated by six O atoms from three chloranilate ions and two saccharin ligands in a distorted octa-hedral geometry. There is an intra-molecular N - H⋯O hydrogen bond between the saccharin ligand and the chloranilate dianion. Each O atom of the chloranilate ion bonds to two NaI atoms, while the saccharin ligand bridges the NaI atoms via the carbonyl O atom and one of the sulfonyl O atoms. The Na atoms and bridging ligands form layers parallel to the ab plane at z = 0 and z = . The shortest Na⋯Na and Na⋯Cl distances in the layer are 3.6006 (12) and 3.0680 (7) {\AA}, respectively.",
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