Abstract
PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of Si-H bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.
| Original language | English |
|---|---|
| Pages (from-to) | 2059-2061 |
| Number of pages | 3 |
| Journal | Tetrahedron Letters |
| Volume | 43 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Mar 11 2002 |
| Externally published | Yes |
Keywords
- Addition reactions
- Cyclopropanes
- Platinum
- Silicon and compounds
- Thorpe-Ingold effect
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Nishihara, Y., Itazaki, M., & Osakada, K. (2002). Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane. Tetrahedron Letters, 43(11), 2059-2061. https://doi.org/10.1016/S0040-4039(02)00165-X