Abstract
PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of Si-H bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.
| Original language | English |
|---|---|
| Pages (from-to) | 2059-2061 |
| Number of pages | 3 |
| Journal | Tetrahedron Letters |
| Volume | 43 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Mar 11 2002 |
| Externally published | Yes |
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Keywords
- Addition reactions
- Cyclopropanes
- Platinum
- Silicon and compounds
- Thorpe-Ingold effect
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
Cite this
Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane. / Nishihara, Yasushi; Itazaki, Masumi; Osakada, Kohtaro.
In: Tetrahedron Letters, Vol. 43, No. 11, 11.03.2002, p. 2059-2061.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane
AU - Nishihara, Yasushi
AU - Itazaki, Masumi
AU - Osakada, Kohtaro
PY - 2002/3/11
Y1 - 2002/3/11
N2 - PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of Si-H bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.
AB - PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of Si-H bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.
KW - Addition reactions
KW - Cyclopropanes
KW - Platinum
KW - Silicon and compounds
KW - Thorpe-Ingold effect
UR - http://www.scopus.com/inward/record.url?scp=0037060938&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037060938&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(02)00165-X
DO - 10.1016/S0040-4039(02)00165-X
M3 - Article
AN - SCOPUS:0037060938
VL - 43
SP - 2059
EP - 2061
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 11
ER -