Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane

Yasushi Nishihara, Masumi Itazaki, Kohtaro Osakada

Research output: Contribution to journal › Article

23 Citations (Scopus)

Abstract

PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of Si-H bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.

Original languageEnglish
Pages (from-to)2059-2061
Number of pages3
JournalTetrahedron Letters
Volume43
Issue number11
DOIs
Publication statusPublished - Mar 11 2002
Externally publishedYes

Fingerprint

Hydrosilylation
Platinum
Silanes
Derivatives
cyclopropane
methylenecyclopropane
diphenyl

Keywords

  • Addition reactions
  • Cyclopropanes
  • Platinum
  • Silicon and compounds
  • Thorpe-Ingold effect

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane. / Nishihara, Yasushi; Itazaki, Masumi; Osakada, Kohtaro.

In: Tetrahedron Letters, Vol. 43, No. 11, 11.03.2002, p. 2059-2061.

Research output: Contribution to journal › Article

Nishihara, Y, Itazaki, M & Osakada, K 2002, 'Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane', Tetrahedron Letters, vol. 43, no. 11, pp. 2059-2061. https://doi.org/10.1016/S0040-4039(02)00165-X
Nishihara Y, Itazaki M, Osakada K. Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane. Tetrahedron Letters. 2002 Mar 11;43(11):2059-2061. https://doi.org/10.1016/S0040-4039(02)00165-X
Nishihara, Yasushi ; Itazaki, Masumi ; Osakada, Kohtaro. / Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane. In: Tetrahedron Letters. 2002 ; Vol. 43, No. 11. pp. 2059-2061.
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