Photoion yield curves of Dy@C82 in the vacuum UV region

Koichiro Mitsuke, Takanori Mori, Junkei Kou, Yusuke Haruyama, Yasuhiro Takabayashi, Yoshihiro Kubozono

    Research output: Contribution to journalArticlepeer-review

    15 Citations (Scopus)

    Abstract

    The photoion yield curves for Dy@C82z+ (z = 1 and 2) from Dy@C82 are measured by using synchrotron radiation in the photon energy range from 24.5 to 39.5 eV. Correction has been made to compensate the effect of transient change of the density of Dy@C82 in the interaction region, with the help of the yield curve of C60 z+ produced from C60 remaining as a trace impurity in the sample. The yield of Dy@C82+ exhibits a gradually descending curve with a flat region at 30-33 eV, similarly to the yield curve of C60+ from C60. The total photoabsorption cross section of Dy@C82 was evaluated to be (1.2 ± 0.4) × 10-20 m2 at the photon energy of 39.5 eV.

    Original languageEnglish
    Pages (from-to)121-125
    Number of pages5
    JournalInternational Journal of Mass Spectrometry
    Volume243
    Issue number2
    DOIs
    Publication statusPublished - May 15 2005

    Keywords

    • Dy@C
    • Metal endohedral fullerenes
    • Metallofullerenes
    • Photoabsorption
    • Vacuum ultraviolet

    ASJC Scopus subject areas

    • Instrumentation
    • Condensed Matter Physics
    • Spectroscopy
    • Physical and Theoretical Chemistry

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