Photoemission from Cr 2p and 3s levels of CrF2

Kozo Okada, Akio Kotani, V. Kinsinger, R. Zimmermann, S. Hüfner

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

We present the experimental and theoretical spectra for photoemission from the 2p- and 3s-core levels in CrF2. By consistently analyzing both spectra, we show that the covalency effect in CrF2 is fairly important, compared with MnF2 and FeF2. This situation occurs as a result of the discontinuous change in the effective charge-transfer energy on going from CrF2 to MnF2.

Original languageEnglish
Pages (from-to)2410-2415
Number of pages6
JournalJournal of the Physical Society of Japan
Volume63
Issue number6
Publication statusPublished - Jun 1994
Externally publishedYes

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photoelectric emission
charge transfer
energy

Keywords

  • 2p
  • 3s
  • Charge transfer
  • Cluster model
  • Configuration interaction
  • Core level
  • Cr
  • CrF
  • Electronic state
  • Exchange splitting
  • Hybridization
  • Multiplet structure
  • Photoemission

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Okada, K., Kotani, A., Kinsinger, V., Zimmermann, R., & Hüfner, S. (1994). Photoemission from Cr 2p and 3s levels of CrF2. Journal of the Physical Society of Japan, 63(6), 2410-2415.

Photoemission from Cr 2p and 3s levels of CrF2. / Okada, Kozo; Kotani, Akio; Kinsinger, V.; Zimmermann, R.; Hüfner, S.

In: Journal of the Physical Society of Japan, Vol. 63, No. 6, 06.1994, p. 2410-2415.

Research output: Contribution to journalArticle

Okada, K, Kotani, A, Kinsinger, V, Zimmermann, R & Hüfner, S 1994, 'Photoemission from Cr 2p and 3s levels of CrF2', Journal of the Physical Society of Japan, vol. 63, no. 6, pp. 2410-2415.
Okada K, Kotani A, Kinsinger V, Zimmermann R, Hüfner S. Photoemission from Cr 2p and 3s levels of CrF2. Journal of the Physical Society of Japan. 1994 Jun;63(6):2410-2415.
Okada, Kozo ; Kotani, Akio ; Kinsinger, V. ; Zimmermann, R. ; Hüfner, S. / Photoemission from Cr 2p and 3s levels of CrF2. In: Journal of the Physical Society of Japan. 1994 ; Vol. 63, No. 6. pp. 2410-2415.
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