Photochemical behavior of 2,5-di-tert-butyl-3H-azepine: Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative

K. Satake; S. Takami; Y. Tawada; M. Kimura

doi:10.1039/b101225h

Photochemical behavior of 2,5-di-tert-butyl-3H-azepine: Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative

K. Satake, S. Takami, Y. Tawada, M. Kimura

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.

Original language	English
Pages (from-to)	1382-1383
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/b101225h
Publication status	Published - Aug 7 2001

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b101225h

Cite this

@article{90104f0e845e42a8ac0aa16dda73c412,

title = "Photochemical behavior of 2,5-di-tert-butyl-3H-azepine: Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative",

abstract = "Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.",

author = "K. Satake and S. Takami and Y. Tawada and M. Kimura",

year = "2001",

month = aug,

day = "7",

doi = "10.1039/b101225h",

language = "English",

pages = "1382--1383",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - Photochemical behavior of 2,5-di-tert-butyl-3H-azepine

T2 - Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative

AU - Satake, K.

AU - Takami, S.

AU - Tawada, Y.

AU - Kimura, M.

PY - 2001/8/7

Y1 - 2001/8/7

N2 - Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.

AB - Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.

UR - http://www.scopus.com/inward/record.url?scp=0035822760&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035822760&partnerID=8YFLogxK

U2 - 10.1039/b101225h

DO - 10.1039/b101225h

M3 - Article

AN - SCOPUS:0035822760

SN - 1359-7345

SP - 1382

EP - 1383

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Photochemical behavior of 2,5-di-tert-butyl-3H-azepine: Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this