Photochemical behavior of 2,5-di-tert-butyl-3H-azepine

Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative

Kyosuke Satake, S. Takami, Y. Tawada, M. Kimura

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.

Original languageEnglish
Pages (from-to)1382-1383
Number of pages2
JournalChemical Communications
Issue number15
Publication statusPublished - Aug 7 2001

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Azepines
Hexane
Pyridine
Irradiation
Derivatives
Hexanes
pyridine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.",
author = "Kyosuke Satake and S. Takami and Y. Tawada and M. Kimura",
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journal = "Chemical Communications",
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T2 - Unexpected formation of a dicyclopenta[b,e]pyridine derivative and a cis,cis-cyclodeca- 1,6-diene derivative

AU - Satake, Kyosuke

AU - Takami, S.

AU - Tawada, Y.

AU - Kimura, M.

PY - 2001/8/7

Y1 - 2001/8/7

N2 - Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.

AB - Hitherto unknown photochemical behavior of 3H-azepine giving cyclopent[c]azete and a (4π + 4π) photodimer is reported on the basis of an unexpected formation of a tricyclic dicyclopenta[b,e]pyridine derivative and a ten-membered-ring dicarbaldehyde by irradiation of 2,5-di-tert-butyl-3H-azepine in hexane.

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