Abstract
Peripherally ethynylated carbazole-based core-modified porphyrins were synthesized by sequential metal-catalyzed coupling and annulation reactions. Experimental results and DFT calculations both confirm that the π-conjugated networks of the resulting porphyrins effectively delocalize over the entire macrocycle, including the ethynyl substituent groups.
Original language | English |
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Pages (from-to) | 5182-5185 |
Number of pages | 4 |
Journal | Organic and Biomolecular Chemistry |
Volume | 10 |
Issue number | 27 |
DOIs | |
Publication status | Published - Jul 21 2012 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry