Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters

Koichi Mitsudo; Takuya Shiraga; Daisuke Kagen; Deqing Shi; James Y. Becker; Hideo Tanaka

doi:10.1016/j.tet.2009.08.004

Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters

Koichi Mitsudo, Takuya Shiraga, Daisuke Kagen, Deqing Shi, James Y. Becker, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

A facile electrooxidative method for synthesizing biaryls from arylboronic acids or arylboronic esters is described. In the presence of a catalytic amount of Pd(OAc)₂ and TEMPO, the electrooxidation of arylboronic acids or arylboronates gave the corresponding biaryls in moderate to excellent yields.

Original language	English
Pages (from-to)	8384-8388
Number of pages	5
Journal	Tetrahedron
Volume	65
Issue number	40
DOIs	https://doi.org/10.1016/j.tet.2009.08.004
Publication status	Published - Oct 3 2009

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "A facile electrooxidative method for synthesizing biaryls from arylboronic acids or arylboronic esters is described. In the presence of a catalytic amount of Pd(OAc)2 and TEMPO, the electrooxidation of arylboronic acids or arylboronates gave the corresponding biaryls in moderate to excellent yields.",

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AU - Mitsudo, Koichi

AU - Shiraga, Takuya

AU - Kagen, Daisuke

AU - Shi, Deqing

AU - Becker, James Y.

AU - Tanaka, Hideo

PY - 2009/10/3

Y1 - 2009/10/3

N2 - A facile electrooxidative method for synthesizing biaryls from arylboronic acids or arylboronic esters is described. In the presence of a catalytic amount of Pd(OAc)2 and TEMPO, the electrooxidation of arylboronic acids or arylboronates gave the corresponding biaryls in moderate to excellent yields.

AB - A facile electrooxidative method for synthesizing biaryls from arylboronic acids or arylboronic esters is described. In the presence of a catalytic amount of Pd(OAc)2 and TEMPO, the electrooxidation of arylboronic acids or arylboronates gave the corresponding biaryls in moderate to excellent yields.

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DO - 10.1016/j.tet.2009.08.004

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JO - Tetrahedron

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