Pd(OAc) 2/o-chloranil/M(OTf) n: A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes

Katsuaki Kawasumi; Kenji Mochida; Tomonori Kajino; Yasutomo Segawa; Kenichiro Itami

doi:10.1021/ol203235w

Pd(OAc) ₂/o-chloranil/M(OTf) _n: A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes

Katsuaki Kawasumi, Kenji Mochida, Tomonori Kajino, Yasutomo Segawa, Kenichiro Itami

Research Core for Interdisciplinary Sciences

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Pd(OAc) ₂/o-chloranil/M(OTf) _n can effectively promote the C-H arylation of fluoranthene with arylboron compounds or arylsilanes. The reaction takes place with high regioselectivity at the C3 position of fluoranthene. Moreover, the new catalytic system allows the use of unfunctionalized arenes as coupling partners in the arylation of polycyclic aromatic hydrocarbons.

Original language	English
Pages (from-to)	418-421
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	1
DOIs	https://doi.org/10.1021/ol203235w
Publication status	Published - Jan 6 2012

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol203235w

Fingerprint Dive into the research topics of 'Pd(OAc) <sub>2</sub>/o-chloranil/M(OTf) <sub>n</sub>: A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes'. Together they form a unique fingerprint.

Cite this

Pd(OAc) ₂/o-chloranil/M(OTf) _n : A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes. / Kawasumi, Katsuaki; Mochida, Kenji; Kajino, Tomonori; Segawa, Yasutomo; Itami, Kenichiro.

In: Organic Letters, Vol. 14, No. 1, 06.01.2012, p. 418-421.

Research output: Contribution to journal › Article › peer-review

@article{0b7a06e5bab74463bbb831f421ba3609,

title = "Pd(OAc) 2/o-chloranil/M(OTf) n: A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes",

abstract = "Pd(OAc) 2/o-chloranil/M(OTf) n can effectively promote the C-H arylation of fluoranthene with arylboron compounds or arylsilanes. The reaction takes place with high regioselectivity at the C3 position of fluoranthene. Moreover, the new catalytic system allows the use of unfunctionalized arenes as coupling partners in the arylation of polycyclic aromatic hydrocarbons.",

author = "Katsuaki Kawasumi and Kenji Mochida and Tomonori Kajino and Yasutomo Segawa and Kenichiro Itami",

year = "2012",

month = jan,

day = "6",

doi = "10.1021/ol203235w",

language = "English",

volume = "14",

pages = "418--421",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Pd(OAc) 2/o-chloranil/M(OTf) n

T2 - A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes

AU - Kawasumi, Katsuaki

AU - Mochida, Kenji

AU - Kajino, Tomonori

AU - Segawa, Yasutomo

AU - Itami, Kenichiro

PY - 2012/1/6

Y1 - 2012/1/6

N2 - Pd(OAc) 2/o-chloranil/M(OTf) n can effectively promote the C-H arylation of fluoranthene with arylboron compounds or arylsilanes. The reaction takes place with high regioselectivity at the C3 position of fluoranthene. Moreover, the new catalytic system allows the use of unfunctionalized arenes as coupling partners in the arylation of polycyclic aromatic hydrocarbons.

AB - Pd(OAc) 2/o-chloranil/M(OTf) n can effectively promote the C-H arylation of fluoranthene with arylboron compounds or arylsilanes. The reaction takes place with high regioselectivity at the C3 position of fluoranthene. Moreover, the new catalytic system allows the use of unfunctionalized arenes as coupling partners in the arylation of polycyclic aromatic hydrocarbons.

UR - http://www.scopus.com/inward/record.url?scp=84855490337&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84855490337&partnerID=8YFLogxK

U2 - 10.1021/ol203235w

DO - 10.1021/ol203235w

M3 - Article

C2 - 22188556

AN - SCOPUS:84855490337

VL - 14

SP - 418

EP - 421

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 1