Pd(OAc) 2/o-chloranil/M(OTf) n

A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes

Katsuaki Kawasumi, Kenji Mochida, Tomonori Kajino, Yasutomo Segawa, Kenichiro Itami

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Pd(OAc) 2/o-chloranil/M(OTf) n can effectively promote the C-H arylation of fluoranthene with arylboron compounds or arylsilanes. The reaction takes place with high regioselectivity at the C3 position of fluoranthene. Moreover, the new catalytic system allows the use of unfunctionalized arenes as coupling partners in the arylation of polycyclic aromatic hydrocarbons.

Original languageEnglish
Pages (from-to)418-421
Number of pages4
JournalOrganic Letters
Volume14
Issue number1
DOIs
Publication statusPublished - Jan 6 2012
Externally publishedYes

Fingerprint

Polycyclic Aromatic Hydrocarbons
polycyclic aromatic hydrocarbons
catalysts
Regioselectivity
Catalysts
fluoranthene
2-chloranil
palladium(II) acetate

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

Cite this

Pd(OAc) 2/o-chloranil/M(OTf) n : A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes. / Kawasumi, Katsuaki; Mochida, Kenji; Kajino, Tomonori; Segawa, Yasutomo; Itami, Kenichiro.

In: Organic Letters, Vol. 14, No. 1, 06.01.2012, p. 418-421.

Research output: Contribution to journalArticle

Kawasumi, Katsuaki ; Mochida, Kenji ; Kajino, Tomonori ; Segawa, Yasutomo ; Itami, Kenichiro. / Pd(OAc) 2/o-chloranil/M(OTf) n : A catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes. In: Organic Letters. 2012 ; Vol. 14, No. 1. pp. 418-421.
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