Pd/NHC-catalyzed cross-coupling reactions of nitroarenes

Myuto Kashihara, Rong Lin Zhong, Kazuhiko Semba, Shigeyoshi Sakaki, Yoshiaki Nakao

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.

Original languageEnglish
Pages (from-to)9291-9294
Number of pages4
JournalChemical Communications
Volume55
Issue number63
DOIs
Publication statusPublished - 2019
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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