Abstract
A reaction of [PdCl2(cod)] (cod = 1,5-cyclooctadiene) and an E/Z mixture of quinoline-2-carbaldehyde (pyridine-2-carbonyl)hydrazone (HL) gave two kinds of PdII mononuclear complexes, [PdCl(Z-L-κ3N,N′,N″)] (1) and [PdCl2(E-HL′-κ2N,N′)] (2), where L- is the deprotonated hydrazonate anion and HL′ is the quinolinium-hydrazonate zwitterionic form of HL. Complex 2 is gradually converted to 1 in solution, and complex 1 is a good precursor to prepare a PdII/RuII heterodinuclear complex bridged by hydrazonate, trans(Cl,Cl)-[RuCl2(PPh3)2(μ-L)PdCl] (3).
Original language | English |
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Pages (from-to) | 15757-15760 |
Number of pages | 4 |
Journal | Dalton Transactions |
Volume | 44 |
Issue number | 36 |
DOIs | |
Publication status | Published - Jul 31 2015 |
ASJC Scopus subject areas
- Inorganic Chemistry