Abstract
A reaction of [PdCl2(cod)] (cod = 1,5-cyclooctadiene) and an E/Z mixture of quinoline-2-carbaldehyde (pyridine-2-carbonyl)hydrazone (HL) gave two kinds of PdII mononuclear complexes, [PdCl(Z-L-κ3N,N′,N″)] (1) and [PdCl2(E-HL′-κ2N,N′)] (2), where L- is the deprotonated hydrazonate anion and HL′ is the quinolinium-hydrazonate zwitterionic form of HL. Complex 2 is gradually converted to 1 in solution, and complex 1 is a good precursor to prepare a PdII/RuII heterodinuclear complex bridged by hydrazonate, trans(Cl,Cl)-[RuCl2(PPh3)2(μ-L)PdCl] (3).
| Original language | English |
|---|---|
| Pages (from-to) | 15757-15760 |
| Number of pages | 4 |
| Journal | Dalton Transactions |
| Volume | 44 |
| Issue number | 36 |
| DOIs | |
| Publication status | Published - Jul 31 2015 |
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ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Palladium(ii) mononuclear and palladium(ii)/ruthenium(ii) heterodinuclear complexes containing 2-quinolyl-substituted (pyridine-2-carbonyl)hydrazone. / Mori, Asami; Suzuki, Takayoshi; Nakatani, Yuichi; Sunatsuki, Yukinari; Kojima, Masaaki; Nakajima, Kiyohiko.
In: Dalton Transactions, Vol. 44, No. 36, 31.07.2015, p. 15757-15760.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Palladium(ii) mononuclear and palladium(ii)/ruthenium(ii) heterodinuclear complexes containing 2-quinolyl-substituted (pyridine-2-carbonyl)hydrazone
AU - Mori, Asami
AU - Suzuki, Takayoshi
AU - Nakatani, Yuichi
AU - Sunatsuki, Yukinari
AU - Kojima, Masaaki
AU - Nakajima, Kiyohiko
PY - 2015/7/31
Y1 - 2015/7/31
N2 - A reaction of [PdCl2(cod)] (cod = 1,5-cyclooctadiene) and an E/Z mixture of quinoline-2-carbaldehyde (pyridine-2-carbonyl)hydrazone (HL) gave two kinds of PdII mononuclear complexes, [PdCl(Z-L-κ3N,N′,N″)] (1) and [PdCl2(E-HL′-κ2N,N′)] (2), where L- is the deprotonated hydrazonate anion and HL′ is the quinolinium-hydrazonate zwitterionic form of HL. Complex 2 is gradually converted to 1 in solution, and complex 1 is a good precursor to prepare a PdII/RuII heterodinuclear complex bridged by hydrazonate, trans(Cl,Cl)-[RuCl2(PPh3)2(μ-L)PdCl] (3).
AB - A reaction of [PdCl2(cod)] (cod = 1,5-cyclooctadiene) and an E/Z mixture of quinoline-2-carbaldehyde (pyridine-2-carbonyl)hydrazone (HL) gave two kinds of PdII mononuclear complexes, [PdCl(Z-L-κ3N,N′,N″)] (1) and [PdCl2(E-HL′-κ2N,N′)] (2), where L- is the deprotonated hydrazonate anion and HL′ is the quinolinium-hydrazonate zwitterionic form of HL. Complex 2 is gradually converted to 1 in solution, and complex 1 is a good precursor to prepare a PdII/RuII heterodinuclear complex bridged by hydrazonate, trans(Cl,Cl)-[RuCl2(PPh3)2(μ-L)PdCl] (3).
UR - http://www.scopus.com/inward/record.url?scp=84940839473&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84940839473&partnerID=8YFLogxK
U2 - 10.1039/c5dt02345a
DO - 10.1039/c5dt02345a
M3 - Article
AN - SCOPUS:84940839473
VL - 44
SP - 15757
EP - 15760
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 36
ER -