Abstract
Palladium-catalyzed decarbonylative alkylation reactions of acyl fluorides have been developed using alkylboranes having β-hydrogens. A wide range of functional groups were well tolerated, even at the high temperature required for decarbonylation. This protocol provides a diverse C(sp2)-C(sp3) bond formation via a highly efficient decarbonylative process. The hemilabile bidentate ligand DPPE plays a crucial role for retardation of the undesired β-hydride elimination.
Original language | English |
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Journal | ACS Applied Materials and Interfaces |
DOIs | |
Publication status | Accepted/In press - Jan 1 2020 |
ASJC Scopus subject areas
- Materials Science(all)