Palladium-catalyzed cross-coupling polycondensation of bisalkynes with dihaloarenes activated by tetrabutylammonium hydroxide or silver(I) oxide

Atsunori Mori; Tatsuhiro Kondo; Tsuyoshi Kato; Yasushi Nishihara

doi:10.1246/cl.2001.286

Palladium-catalyzed cross-coupling polycondensation of bisalkynes with dihaloarenes activated by tetrabutylammonium hydroxide or silver(I) oxide

Atsunori Mori, Tatsuhiro Kondo, Tsuyoshi Kato, Yasushi Nishihara

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

The palladium(0)-catalyzed polycondensation of bis-trimethylsilylethynylated compounds with diiodoarenes to give the polymers bearing arylene-ethynylene moieties is carried out by the use of silver(I) oxide as an activator. Polycondensation of bifunctional terminal alkynes and aryl halides is also accomplished by the palladium-catalyzed cross coupling in the presence of tetrabutylammonium hydroxide (TBAOH), tetrabutylammonium fluoride (TBAF), or silver(I) oxide.

Original language	English
Pages (from-to)	286-287
Number of pages	2
Journal	Chemistry Letters
Issue number	4
DOIs	https://doi.org/10.1246/cl.2001.286
Publication status	Published - Jan 1 2001
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2001.286

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title = "Palladium-catalyzed cross-coupling polycondensation of bisalkynes with dihaloarenes activated by tetrabutylammonium hydroxide or silver(I) oxide",

abstract = "The palladium(0)-catalyzed polycondensation of bis-trimethylsilylethynylated compounds with diiodoarenes to give the polymers bearing arylene-ethynylene moieties is carried out by the use of silver(I) oxide as an activator. Polycondensation of bifunctional terminal alkynes and aryl halides is also accomplished by the palladium-catalyzed cross coupling in the presence of tetrabutylammonium hydroxide (TBAOH), tetrabutylammonium fluoride (TBAF), or silver(I) oxide.",

author = "Atsunori Mori and Tatsuhiro Kondo and Tsuyoshi Kato and Yasushi Nishihara",

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AU - Kato, Tsuyoshi

AU - Nishihara, Yasushi

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The palladium(0)-catalyzed polycondensation of bis-trimethylsilylethynylated compounds with diiodoarenes to give the polymers bearing arylene-ethynylene moieties is carried out by the use of silver(I) oxide as an activator. Polycondensation of bifunctional terminal alkynes and aryl halides is also accomplished by the palladium-catalyzed cross coupling in the presence of tetrabutylammonium hydroxide (TBAOH), tetrabutylammonium fluoride (TBAF), or silver(I) oxide.

AB - The palladium(0)-catalyzed polycondensation of bis-trimethylsilylethynylated compounds with diiodoarenes to give the polymers bearing arylene-ethynylene moieties is carried out by the use of silver(I) oxide as an activator. Polycondensation of bifunctional terminal alkynes and aryl halides is also accomplished by the palladium-catalyzed cross coupling in the presence of tetrabutylammonium hydroxide (TBAOH), tetrabutylammonium fluoride (TBAF), or silver(I) oxide.

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Palladium-catalyzed cross-coupling polycondensation of bisalkynes with dihaloarenes activated by tetrabutylammonium hydroxide or silver(I) oxide

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